Formulas & Equation Cheat-Sheets
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Trigonometry Formulas Suite
Identities, double angles, triangle laws, Euler formula
Standard Unit Circle Angle Values Table
Exact trigonometric ratios for common benchmark angles in degrees and radians
| Degrees (x) | Radians (rad) | sin(x) | cos(x) | tan(x) | csc(x) | sec(x) | cot(x) |
|---|---|---|---|---|---|---|---|
| 0° | 0 | 0 | 1 | 0 | undefined | 1 | undefined |
| 30° | π/6 | 1/2 | √3/2 | √3/3 | 2 | 2√3/3 | √3 |
| 45° | π/4 | √2/2 | √2/2 | 1 | √2 | √2 | 1 |
| 60° | π/3 | √3/2 | 1/2 | √3 | 2√3/3 | 2 | √3/3 |
| 90° | π/2 | 1 | 0 | undefined | 1 | undefined | 0 |
| 120° | 2π/3 | √3/2 | -1/2 | -√3 | 2√3/3 | -2 | -√3/3 |
| 135° | 3π/4 | √2/2 | -√2/2 | -1 | √2 | -√2 | -1 |
| 150° | 5π/6 | 1/2 | -√3/2 | -√3/3 | 2 | -2√3/3 | -√3 |
| 180° | π | 0 | -1 | 0 | undefined | -1 | undefined |
| 270° | 3π/2 | -1 | 0 | undefined | -1 | undefined | 0 |
| 360° | 2π | 0 | 1 | 0 | undefined | 1 | undefined |
🔄 Reciprocal & Quotient Identities
8 formulas Fundamental relations between primary and reciprocal trigonometric ratios
Reciprocal & Quotient Identities
8 formulasFundamental relations between primary and reciprocal trigonometric ratios
Sine Reciprocal
sin(x) = 1csc(x) csc(x) ≠ 0; x ≠ nπ
Cosecant Reciprocal
csc(x) = 1sin(x) sin(x) ≠ 0; x ≠ nπ
Cosine Reciprocal
cos(x) = 1sec(x) sec(x) ≠ 0; x ≠ (2n+1)π/2
Secant Reciprocal
sec(x) = 1cos(x) cos(x) ≠ 0; x ≠ (2n+1)π/2
Tangent Reciprocal
tan(x) = 1cot(x) cot(x) ≠ 0; x ≠ nπ/2
Cotangent Reciprocal
cot(x) = 1tan(x) tan(x) ≠ 0; x ≠ nπ/2
Tangent Quotient
tan(x) = sin(x)cos(x) Ratio of Opposite to Adjacent in a right triangle
Cotangent Quotient
cot(x) = cos(x)sin(x) Ratio of Adjacent to Opposite in a right triangle
🪞 Opposite Angle Formulas (Even & Odd Functions)
6 formulas Symmetry behavior of trigonometric functions under angle negation
Opposite Angle Formulas (Even & Odd Functions)
6 formulasSymmetry behavior of trigonometric functions under angle negation
Sine Negative Angle (Odd Function)
sin(-x) = -sin(x) Symmetric with respect to the origin
Cosine Negative Angle (Even Function)
cos(-x) = cos(x) Symmetric with respect to the y-axis
Tangent Negative Angle (Odd Function)
tan(-x) = -tan(x) Odd symmetry around origin
Cotangent Negative Angle (Odd Function)
cot(-x) = -cot(x) Odd symmetry around origin
Secant Negative Angle (Even Function)
sec(-x) = sec(x) Inherits even symmetry from cosine
Cosecant Negative Angle (Odd Function)
csc(-x) = -csc(x) Inherits odd symmetry from sine
📐 Cofunction Formulas (Complementary Angles)
6 formulas Identities connecting trigonometric functions of complementary angles (π/2 - x or 90° - x)
Cofunction Formulas (Complementary Angles)
6 formulasIdentities connecting trigonometric functions of complementary angles (π/2 - x or 90° - x)
Sine Cofunction
sin(π2- x) = cos(x) Also: sin(90° - x) = cos(x)
Cosine Cofunction
cos(π2- x) = sin(x) Also: cos(90° - x) = sin(x)
Tangent Cofunction
tan(π2- x) = cot(x) Also: tan(90° - x) = cot(x)
Cotangent Cofunction
cot(π2- x) = tan(x) Also: cot(90° - x) = tan(x)
Secant Cofunction
sec(π2- x) = csc(x) Also: sec(90° - x) = csc(x)
Cosecant Cofunction
csc(π2- x) = sec(x) Also: csc(90° - x) = sec(x)
🔺 Pythagorean Identities & Algebraic Forms
9 formulas Derived directly from the unit circle (x² + y² = 1) and right-triangle trigonometry
Pythagorean Identities & Algebraic Forms
9 formulasDerived directly from the unit circle (x² + y² = 1) and right-triangle trigonometry
Primary Pythagorean Identity
sin²(x) + cos²(x) = 1 Fundamental identity valid for all real angles x
Sine in terms of Cosine
sin(x) = ±√1 - cos²(x) Sign chosen based on quadrant of x
Cosine in terms of Sine
cos(x) = ±√1 - sin²(x) Sign chosen based on quadrant of x
Tangent-Secant Pythagorean Identity
1 + tan²(x) = sec²(x) Obtained by dividing sin²(x) + cos²(x) = 1 by cos²(x)
Secant-Tangent Difference Form
sec²(x) - tan²(x) = 1 Valid where cos(x) ≠ 0
Cotangent-Cosecant Pythagorean Identity
1 + cot²(x) = csc²(x) Obtained by dividing sin²(x) + cos²(x) = 1 by sin²(x)
Cosecant-Cotangent Difference Form
csc²(x) - cot²(x) = 1 Valid where sin(x) ≠ 0
Unit Circle Radical Normalization
√sin²(x) + cos²(x) = 1 Geometric hypotenuse length on unit circle
Product Unity Identities
sin(x)·csc(x) = 1, cos(x)·sec(x) = 1, tan(x)·cot(x) = 1 Reciprocal products equal unity
➕ Angle Addition & Subtraction (Compound Angles)
8 formulas Formulas for the trigonometric ratios of the sum and difference of two angles (A ± B)
Angle Addition & Subtraction (Compound Angles)
8 formulasFormulas for the trigonometric ratios of the sum and difference of two angles (A ± B)
Sine of Angle Sum
sin(A + B) = sin(A)cos(B) + cos(A)sin(B) Key compound angle formula for sine addition
Sine of Angle Difference
sin(A - B) = sin(A)cos(B) - cos(A)sin(B) Key compound angle formula for sine difference
Cosine of Angle Sum
cos(A + B) = cos(A)cos(B) - sin(A)sin(B) Notice the minus sign in cosine sum expansion
Cosine of Angle Difference
cos(A - B) = cos(A)cos(B) + sin(A)sin(B) Notice the plus sign in cosine difference expansion
Tangent of Angle Sum
tan(A + B) = tan(A) + tan(B)1 - tan(A)tan(B) Requires tan(A)tan(B) ≠ 1
Tangent of Angle Difference
tan(A - B) = tan(A) - tan(B)1 + tan(A)tan(B) Requires tan(A)tan(B) ≠ -1
Cotangent of Angle Sum
cot(A + B) = cot(A)cot(B) - 1cot(B) + cot(A) Compound formula for cotangent sum
Cotangent of Angle Difference
cot(A - B) = cot(A)cot(B) + 1cot(B) - cot(A) Compound formula for cotangent difference
✖️2️⃣ Double Angle Formulas (2x)
7 formulas Expressing functions of double angle (2x) in terms of single angle (x)
Double Angle Formulas (2x)
7 formulasExpressing functions of double angle (2x) in terms of single angle (x)
Sine Double Angle
sin(2x) = 2 sin(x) cos(x) Includes rational tangent parametrization form
Cosine Double Angle (Standard Difference)
cos(2x) = cos²(x) - sin²(x) Direct consequence of cos(x + x)
Cosine Double Angle (Cosine Only)
cos(2x) = 2 cos²(x) - 1 Crucial for integration and power reduction
Cosine Double Angle (Sine Only)
cos(2x) = 1 - 2 sin²(x) Crucial for integration and half-angle derivation
Cosine Double Angle (Tangent Parametrization)
cos(2x) = 1 - tan²(x)1 + tan²(x) Weierstrass substitution relation for cosine
Tangent Double Angle
tan(2x) = 2 tan(x)1 - tan²(x) Requires tan²(x) ≠ 1
Cotangent Double Angle
cot(2x) = cot²(x) - 12 cot(x) Requires cot(x) ≠ 0
3️⃣ Triple Angle Formulas (3x)
4 formulas Trigonometric functions of 3x expressed in single-angle polynomial forms
Triple Angle Formulas (3x)
4 formulasTrigonometric functions of 3x expressed in single-angle polynomial forms
Sine Triple Angle
sin(3x) = 3 sin(x) - 4 sin³(x) Useful for solving cubic equations and algebra
Cosine Triple Angle
cos(3x) = 4 cos³(x) - 3 cos(x) Direct cubic Chebyshev polynomial T₃(x) = 4x³ - 3x
Tangent Triple Angle
tan(3x) = 3 tan(x) - tan³(x)1 - 3 tan²(x) Requires 3tan²(x) ≠ 1
Cotangent Triple Angle
cot(3x) = 3 cot(x) - cot³(x)1 - 3 cot²(x) Requires 3cot²(x) ≠ 1
½ Half Angle Formulas (x/2)
6 formulas Exact formulas for half angles with sign determined by quadrant of x/2
Half Angle Formulas (x/2)
6 formulasExact formulas for half angles with sign determined by quadrant of x/2
Sine Half Angle
sin(x2) = ±√1 - cos(x)2 ± sign chosen based on the quadrant containing x/2
Cosine Half Angle
cos(x2) = ±√1 + cos(x)2 ± sign chosen based on the quadrant containing x/2
Tangent Half Angle (Radical Form)
tan(x2) = ±√1 - cos(x)1 + cos(x) Square-root half-angle form for tangent
Tangent Half Angle (Rational Form 1)
tan(x2) = 1 - cos(x)sin(x) No sign ambiguity; exact for all x ≠ nπ
Tangent Half Angle (Rational Form 2 / Difference)
tan(x2) = sin(x)1 + cos(x) = csc(x) - cot(x) Equivalent to difference csc(x) - cot(x)
Cotangent Half Angle
cot(x2) = 1 + cos(x)sin(x) = csc(x) + cot(x) Equivalent to sum csc(x) + cot(x)
⚡ Power Reducing Formulas (Squared & Higher Powers)
7 formulas Converts powers of trigonometric functions into first-degree multiples of x (essential for Calculus integration)
Power Reducing Formulas (Squared & Higher Powers)
7 formulasConverts powers of trigonometric functions into first-degree multiples of x (essential for Calculus integration)
Sine Squared Power Reduction
sin²(x) = 1 - cos(2x)2 Fundamental calculus antiderivative reduction: ∫sin²(x)dx
Cosine Squared Power Reduction
cos²(x) = 1 + cos(2x)2 Fundamental calculus antiderivative reduction: ∫cos²(x)dx
Tangent Squared Power Reduction
tan²(x) = 1 - cos(2x)1 + cos(2x) Rational cosine fraction form for tan²(x)
Sine Cubed Power Reduction
sin³(x) = 3 sin(x) - sin(3x)4 Derived directly from sin(3x) triple angle identity
Cosine Cubed Power Reduction
cos³(x) = 3 cos(x) + cos(3x)4 Derived directly from cos(3x) triple angle identity
Sine Fourth Power Reduction
sin⁴(x) = 3 - 4 cos(2x) + cos(4x)8 Used for Fourier series and higher order integrals
Cosine Fourth Power Reduction
cos⁴(x) = 3 + 4 cos(2x) + cos(4x)8 Used for Fourier series and higher order integrals
✖️➡️➕ Product-to-Sum Formulas
4 formulas Converts products of sine and cosine into sum and difference terms (crucial for wave mechanics & integrals)
Product-to-Sum Formulas
4 formulasConverts products of sine and cosine into sum and difference terms (crucial for wave mechanics & integrals)
Sine × Sine Product
sin(A) sin(B) = ½ [cos(A - B) - cos(A + B)] Transforms wave interference products into additive components
Cosine × Cosine Product
cos(A) cos(B) = ½ [cos(A - B) + cos(A + B)] Transforms cosine products into additive components
Sine × Cosine Product
sin(A) cos(B) = ½ [sin(A + B) + sin(A - B)] Standard signal modulation product formula
Cosine × Sine Product
cos(A) sin(B) = ½ [sin(A + B) - sin(A - B)] Complementary product decomposition
➕➡️✖️ Sum-to-Product Formulas
6 formulas Converts sums and differences of trigonometric functions into multiplicative products
Sum-to-Product Formulas
6 formulasConverts sums and differences of trigonometric functions into multiplicative products
Sine + Sine Sum
sin(A) + sin(B) = 2 sin(A + B2) cos(A - B2) Explains beat frequency phenomenon in acoustic wave acoustics
Sine - Sine Difference
sin(A) - sin(B) = 2 sin(A - B2) cos(A + B2) Differential wave analysis form
Cosine + Cosine Sum
cos(A) + cos(B) = 2 cos(A + B2) cos(A - B2) Even sum-to-product conversion
Cosine - Cosine Difference
cos(A) - cos(B) = -2 sin(A + B2) sin(A - B2) Notice the leading negative sign (or reverse order B - A)
Tangent + Tangent Sum
tan(A) + tan(B) = sin(A + B)cos(A) cos(B) Calculates combined tangent slopes
Tangent - Tangent Difference
tan(A) - tan(B) = sin(A - B)cos(A) cos(B) Calculates difference of tangent slopes
📐 Triangle Laws & Geometry Relations
7 formulas Laws for solving general oblique triangles (Law of Sines, Cosines, Tangents, and Mollweide’s formulas)
Triangle Laws & Geometry Relations
7 formulasLaws for solving general oblique triangles (Law of Sines, Cosines, Tangents, and Mollweide’s formulas)
Law of Sines
asin(A) = bsin(B) = csin(C) = 2R R is the radius of the circumscribed circle (circumradius)
Law of Cosines (Side a / Angle A)
a² = b² + c² - 2bc cos(A) Solves SAS (Side-Angle-Side) or SSS (Side-Side-Side)
Law of Cosines (Side b & Side c)
b² = a² + c² - 2ac cos(B), c² = a² + b² - 2ab cos(C) Symmetric versions for sides b and c
Law of Tangents
a - ba + b = tan[½(A - B)]tan[½(A + B)] Historically used for logarithmic computations in navigation
Mollweide's First Formula
a + bc = cos[½(A - B)]sin(½C) Excellent formula for checking triangle solver consistency
Mollweide's Second Formula
a - bc = sin[½(A - B)]cos(½C) Complementary Mollweide consistency relation
Trigonometric Triangle Area (SAS)
Area = ½ a b sin(C) = ½ b c sin(A) = ½ a c sin(B) Calculates area from two sides and included angle
⭕ Arc Length, Sectors & Circular Motion
3 formulas Relations connecting angle in radians to curved distance, sector area, and angular velocity
Arc Length, Sectors & Circular Motion
3 formulasRelations connecting angle in radians to curved distance, sector area, and angular velocity
Arc Length Formula
S = r x Angle x MUST be expressed in radians (x = x° × π / 180°)
Circular Sector Area
Area = ½ r² x = ½ r S x in radians; equals ½ × radius × arc length
Linear Speed & Angular Velocity
v = r ω, ω = xt = 2π f Relates linear tangential speed v to angular velocity ω and frequency f
🌐 Euler's Formula, De Moivre's & Complex Trig
5 formulas Bridge connecting exponential complex analysis and polar trigonometry
Euler's Formula, De Moivre's & Complex Trig
5 formulasBridge connecting exponential complex analysis and polar trigonometry
Euler's Formula
e^(ix) = cos(x) + i sin(x) = cis(x) Connects the exponential function directly with sine and cosine; for x=π gives e^(iπ) + 1 = 0
De Moivre's Formula
(r cis x)ⁿ = rⁿ cis(nx) = rⁿ [cos(nx) + i sin(nx)] Computes powers and roots of complex numbers instantaneously
Polar Multiplication & Division
(r₁ cis x)(r₂ cis φ) = r₁r₂ cis(x + φ),r₁ cis xr₂ cis φ = (r₁r₂) cis(x - φ) Magnitudes multiply/divide; angle arguments add/subtract
Exponential Definition of Cosine
cos(x) = e^(ix) + e^(-ix)2 Expresses cosine algebraically using complex exponentials
Exponential Definition of Sine
sin(x) = e^(ix) - e^(-ix)2i Expresses sine algebraically using complex exponentials
↩️ Inverse Trigonometric Identities
6 formulas Properties, principal value branch identities, and sum formulas for inverse circular functions
Inverse Trigonometric Identities
6 formulasProperties, principal value branch identities, and sum formulas for inverse circular functions
Inverse Complementary Identities
sin⁻¹(x) + cos⁻¹(x) = π2, tan⁻¹(x) + cot⁻¹(x) = π2, sec⁻¹(x) + csc⁻¹(x) = π2 Valid on respective domains: x ∈ [-1, 1], x ∈ ℝ, |x| ≥ 1
Inverse Tangent Sum Formula
tan⁻¹(x) + tan⁻¹(y) = tan⁻¹(x + y1 - xy) If xy > 1 and x,y > 0, add π to the result
Inverse Tangent Difference Formula
tan⁻¹(x) - tan⁻¹(y) = tan⁻¹(x - y1 + xy) Standard inverse tangent subtraction formula
Double Inverse Tangent Multiple Representations
2 tan⁻¹(x) = sin⁻¹(2x1 + x²) = cos⁻¹(1 - x²1 + x²) = tan⁻¹(2x1 - x²) Crucial for calculus Weierstrass t-substitution (t = tan(x/2))
Negative Argument Inverse Identities
sin⁻¹(-x) = -sin⁻¹(x), tan⁻¹(-x) = -tan⁻¹(x), cos⁻¹(-x) = π - cos⁻¹(x) Note that cos⁻¹(-x) produces π - cos⁻¹(x)
Inverse Reciprocal Function Relations
csc⁻¹(x) = sin⁻¹(1x), sec⁻¹(x) = cos⁻¹(1x), cot⁻¹(x) = tan⁻¹(1x) [x > 0] Reciprocal argument mapping for inverse functions
Differentiation Formulas Suite
Derivatives, chain rule, product rule, exponential & logs
⚡ Fundamental Derivative Rules & Operations
9 formulas Core operational differentiation rules for constants, powers, and algebraic combinations
Fundamental Derivative Rules & Operations
9 formulasCore operational differentiation rules for constants, powers, and algebraic combinations
Derivative by First Principles (Limit Definition)
f'(x) = lim[h→0] (f(x + h) - f(x))h Fundamental definition of derivative as instantaneous rate of change
Constant Rule
ddx [c] = 0 The derivative of any constant c is zero
Power Rule
ddx [xⁿ] = n·xⁿ⁻¹ Valid for all real exponents n (n ∈ ℝ)
Constant Multiple Rule
ddx [c·f(x)] = c·f'(x) Constants factor out of differentiation
Sum & Difference Rule
ddx [f(x) ± g(x)] = f'(x) ± g'(x) Differentiation is a linear operator
Product Rule (Leibniz Rule)
ddx [f(x)·g(x)] = f'(x)g(x) + f(x)g'(x) Differentiate first, hold second, plus hold first, differentiate second
Quotient Rule
ddx [f(x)g(x)] = g(x)f'(x) - f(x)g'(x)[g(x)]² Requires g(x) ≠ 0
Chain Rule (Composite Functions)
ddx [f(g(x))] = f'(g(x))·g'(x) Differentiate outer function evaluated at inner, multiply by derivative of inner
Reciprocal Function Rule
ddx [1f(x)] = -f'(x)[f(x)]² Direct shortcut for reciprocating functions
📈 Exponential & Logarithmic Derivatives
7 formulas Derivatives of natural, general base exponentials and logarithmic functions
Exponential & Logarithmic Derivatives
7 formulasDerivatives of natural, general base exponentials and logarithmic functions
Natural Exponential Derivative
ddx [eˣ] = eˣ The unique non-zero function equal to its own derivative
Composite Natural Exponential Derivative
ddx [e^(f(x))] = e^(f(x))·f'(x) Chain rule applied to natural exponential
General Base Exponential Derivative
ddx [aˣ] = aˣ·ln(a) Valid for a > 0, a ≠ 1
Natural Logarithm Derivative
ddx [ln(x)] = 1x For absolute values: d/dx [ln|x|] = 1 / x (x ≠ 0)
Composite Natural Logarithm Derivative
ddx [ln(f(x))] = f'(x)f(x) Logarithmic derivative / relative rate of change
General Base Logarithm Derivative
ddx [loga(x)] = 1x·ln(a) Change of base differentiation formula
Variable Base and Variable Exponent (xˣ)
ddx [xˣ] = xˣ·(1 + ln(x)) Derived using logarithmic differentiation y = xˣ ⇒ ln y = x ln x
📐 Trigonometric Function Derivatives
7 formulas Derivatives of all six standard trigonometric functions (sin, cos, tan, cot, sec, csc)
Trigonometric Function Derivatives
7 formulasDerivatives of all six standard trigonometric functions (sin, cos, tan, cot, sec, csc)
Derivative of Sine
ddx [sin(x)] = cos(x) Rate of change of sine is cosine
Derivative of Cosine
ddx [cos(x)] = -sin(x) Notice the negative sign for "co-" function
Derivative of Tangent
ddx [tan(x)] = sec²(x) Also equal to 1 + tan²(x)
Derivative of Cotangent
ddx [cot(x)] = -csc²(x) Also equal to -(1 + cot²(x))
Derivative of Secant
ddx [sec(x)] = sec(x)·tan(x) Product of secant and tangent
Derivative of Cosecant
ddx [csc(x)] = -csc(x)·cot(x) Product of cosecant and cotangent with negative sign
Composite Trigonometric Chain Form
ddx [sin(f(x))] = cos(f(x))·f'(x), ddx [cos(f(x))] = -sin(f(x))·f'(x) Standard generalized trigonometric chain rule
↩️ Inverse Trigonometric Derivatives
6 formulas Derivatives of inverse sine, cosine, tangent, cotangent, secant, and cosecant
Inverse Trigonometric Derivatives
6 formulasDerivatives of inverse sine, cosine, tangent, cotangent, secant, and cosecant
Derivative of Inverse Sine
ddx [sin⁻¹(x)] = 1√1 - x² Domain strictly between -1 and 1
Derivative of Inverse Cosine
ddx [cos⁻¹(x)] = -1√1 - x² Exact negative of inverse sine derivative
Derivative of Inverse Tangent
ddx [tan⁻¹(x)] = 11 + x² Valid for all real numbers without singularity
Derivative of Inverse Cotangent
ddx [cot⁻¹(x)] = -11 + x² Exact negative of inverse tangent derivative
Derivative of Inverse Secant
ddx [sec⁻¹(x)] = 1|x|·√x² - 1 Requires |x| > 1
Derivative of Inverse Cosecant
ddx [csc⁻¹(x)] = -1|x|·√x² - 1 Exact negative of inverse secant derivative
〰️ Hyperbolic & Inverse Hyperbolic Derivatives
9 formulas Derivatives of sinh, cosh, tanh, and their respective inverse functions
Hyperbolic & Inverse Hyperbolic Derivatives
9 formulasDerivatives of sinh, cosh, tanh, and their respective inverse functions
Derivative of Hyperbolic Sine (sinh x)
ddx [sinh(x)] = cosh(x) Notice no negative sign (unlike regular cosine)
Derivative of Hyperbolic Cosine (cosh x)
ddx [cosh(x)] = sinh(x) Positive rate of change
Derivative of Hyperbolic Tangent (tanh x)
ddx [tanh(x)] = sech²(x) Crucial for neural network activation backpropagation
Derivative of Hyperbolic Cotangent (coth x)
ddx [coth(x)] = -csch²(x) Negative hyperbolic cosecant squared
Derivative of Hyperbolic Secant (sech x)
ddx [sech(x)] = -sech(x)·tanh(x) Negative hyperbolic product
Derivative of Hyperbolic Cosecant (csch x)
ddx [csch(x)] = -csch(x)·coth(x) Negative hyperbolic product
Derivative of Inverse Hyperbolic Sine
ddx [arsinh(x)] = 1√x² + 1 Valid for all real x
Derivative of Inverse Hyperbolic Cosine
ddx [arcosh(x)] = 1√x² - 1 Valid for x > 1
Derivative of Inverse Hyperbolic Tangent
ddx [artanh(x)] = 11 - x² Valid for |x| < 1
🔬 Advanced Differentiation Techniques & Theorems
6 formulas Implicit differentiation, parametric curves, L’Hôpital’s rule, and Taylor expansions
Advanced Differentiation Techniques & Theorems
6 formulasImplicit differentiation, parametric curves, L’Hôpital’s rule, and Taylor expansions
Parametric First Derivative (dy/dx)
dydx = dydtdxdt Calculates curve tangent slope from parametric equations x(t), y(t)
Parametric Second Derivative (d²y/dx²)
d²ydx² = [ddt (dydx)]dxdt Calculates concavity of parametric curves
L'Hôpital's Rule (0/0 or ∞/∞ Limits)
lim[x→c] f(x)g(x) = lim[x→c] f'(x)g'(x) Resolves indeterminate limits by differentiating numerator and denominator independently
Mean Value Theorem (MVT)
f'(c) = f(b) - f(a)b - a Guarantees a point where instantaneous rate of change equals average rate of change
Taylor Series Expansion around x = a
f(x) = ∑[n = 0→∞] (f⁽ⁿ⁾(a)n!)·(x - a)ⁿ Polynomial approximation of smooth differentiable functions
Maclaurin Series Expansion (a = 0)
f(x) = ∑[n = 0→∞] (f⁽ⁿ⁾(0)n!)·xⁿ Taylor series centered at the origin (x = 0)
Integration Formulas Suite
Antiderivatives, parts, partial fractions, reduction formulas
∫ Fundamental Integration Rules & Powers
6 formulas Elementary antiderivative rules for constants, algebraic powers, and linear combinations
Fundamental Integration Rules & Powers
6 formulasElementary antiderivative rules for constants, algebraic powers, and linear combinations
Constant Integral
∫ k dx = k·x + C Antiderivative of a constant k is k·x + C
Power Rule of Integration
∫ xⁿ dx = xⁿ⁺¹n + 1 + C Valid for all real powers n except n = -1
Reciprocal Function Integral (1/x)
∫ (1x) dx = ln|x| + C Crucial special case for n = -1 in power rule
Linearity Rule of Integration
∫ [a·f(x) ± b·g(x)] dx = a ∫ f(x) dx ± b ∫ g(x) dx Integration is a linear functional operation
Linear Composite Power Rule
∫ (ax + b)ⁿ dx = (ax + b)ⁿ⁺¹a(n + 1) + C Shortcut for linear binomial powers
Linear Composite Reciprocal Integral
∫ (1ax + b) dx = (1a)·ln|ax + b| + C Standard linear denominator integration formula
📈 Exponential & Logarithmic Integrals
6 formulas Antiderivatives involving natural eˣ, general base aˣ, and logarithmic terms
Exponential & Logarithmic Integrals
6 formulasAntiderivatives involving natural eˣ, general base aˣ, and logarithmic terms
Natural Exponential Integral
∫ eˣ dx = eˣ + C Function equals its own antiderivative up to constant C
Scaled Exponential Integral (eᵃˣ)
∫ e^(ax) dx = (1a)·e^(ax) + C Standard scaled exponential integration rule
General Base Exponential Integral (aˣ)
∫ aˣ dx = aˣln(a)+ C Divides by ln(a) because derivative multiplied by ln(a)
Natural Logarithm Integral
∫ ln(x) dx = x·ln(x) - x + C Derived using integration by parts with u = ln x, dv = dx
General Base Logarithm Integral
∫ loga(x) dx = x·ln(x) - xln(a)+ C Change of base integration for logarithms
Product Integral (x · eˣ)
∫ x·eˣ dx = eˣ(x - 1) + C Classic integration by parts application
📐 Basic Trigonometric Integrals
6 formulas Direct antiderivatives corresponding to standard trigonometric derivatives
Basic Trigonometric Integrals
6 formulasDirect antiderivatives corresponding to standard trigonometric derivatives
Integral of Sine
∫ sin(x) dx = -cos(x) + C Note the negative sign in antiderivative of sine
Integral of Cosine
∫ cos(x) dx = sin(x) + C Direct standard trigonometric antiderivative
Integral of Secant Squared
∫ sec²(x) dx = tan(x) + C Because derivative of tangent is secant squared
Integral of Cosecant Squared
∫ csc²(x) dx = -cot(x) + C Because derivative of cotangent is -csc²(x)
Integral of Secant × Tangent
∫ sec(x) tan(x) dx = sec(x) + C Direct derivative reversal of sec(x)
Integral of Cosecant × Cotangent
∫ csc(x) cot(x) dx = -csc(x) + C Direct derivative reversal of csc(x)
⚡ Extended & Squared Trigonometric Integrals
8 formulas Integrals of tan, cot, sec, csc, and squared trigonometric terms
Extended & Squared Trigonometric Integrals
8 formulasIntegrals of tan, cot, sec, csc, and squared trigonometric terms
Integral of Tangent
∫ tan(x) dx = ln|sec(x)| + C = -ln|cos(x)| + C Evaluated by substitution u = cos(x)
Integral of Cotangent
∫ cot(x) dx = ln|sin(x)| + C = -ln|csc(x)| + C Evaluated by substitution u = sin(x)
Integral of Secant
∫ sec(x) dx = ln|sec(x) + tan(x)| + C Famous calculus integral multiplied by (sec x + tan x)/(sec x + tan x)
Integral of Cosecant
∫ csc(x) dx = ln|csc(x) - cot(x)| + C = ln|tan(x2)| + C Standard logarithmic cosecant integral
Integral of Sine Squared (sin² x)
∫ sin²(x) dx = (x2) - (sin(2x)4) + C Evaluated using power reduction identity sin²(x) = (1 - cos 2x)/2
Integral of Cosine Squared (cos² x)
∫ cos²(x) dx = (x2) + (sin(2x)4) + C Evaluated using power reduction identity cos²(x) = (1 + cos 2x)/2
Integral of Tangent Squared (tan² x)
∫ tan²(x) dx = tan(x) - x + C Evaluated using identity tan²(x) = sec²(x) - 1
Integral of Cotangent Squared (cot² x)
∫ cot²(x) dx = -cot(x) - x + C Evaluated using identity cot²(x) = csc²(x) - 1
↩️ Integrals Yielding Inverse Trigonometric Functions
5 formulas Standard algebraic fraction integrals whose antiderivatives are inverse trig functions
Integrals Yielding Inverse Trigonometric Functions
5 formulasStandard algebraic fraction integrals whose antiderivatives are inverse trig functions
Integral Yielding Inverse Sine
∫ (1√a² - x²) dx = sin⁻¹(xa) + C Notice no 1/a factor outside for inverse sine
Integral Yielding Inverse Tangent
∫ (1a² + x²) dx = (1a)·tan⁻¹(xa) + C The 1/a coefficient is required unlike inverse sine
Integral Yielding Inverse Secant
∫ (1x·√x² - a²) dx = (1a)·sec⁻¹(|x|a) + C Includes 1/a coefficient and absolute value |x|
Integral of 1 / (x² - a²)
∫ (1x² - a²) dx = (12a)·ln|(x - a)x + a| + C Obtained via partial fraction decomposition 1/(x²-a²)
Integral of 1 / (a² - x²)
∫ (1a² - x²) dx = (12a)·ln|(a + x)a - x| + C Obtained via partial fraction decomposition 1/(a²-x²)
√ Special Radical Square-Root Integrals
4 formulas Standard radical integrals solved via trigonometric substitution (x = a sin θ, a tan θ, a sec θ)
Special Radical Square-Root Integrals
4 formulasStandard radical integrals solved via trigonometric substitution (x = a sin θ, a tan θ, a sec θ)
Integral of √(a² - x²)
∫ √a² - x² dx = (x2)√a² - x² + (a²2)sin⁻¹(xa) + C Used for computing circular and elliptical sector areas
Integral of √(x² + a²)
∫ √x² + a² dx = (x2)√x² + a² + (a²2)ln|x + √x² + a²| + C Solved using substitution x = a tan θ or hyperbolic x = a sinh u
Integral of √(x² - a²)
∫ √x² - a² dx = (x2)√x² - a² - (a²2)ln|x + √x² - a²| + C Solved using substitution x = a sec θ or hyperbolic x = a cosh u
Integral of 1 / √(x² ± a²)
∫ (1√x² ± a²) dx = ln|x + √x² ± a²| + C Also equal to arsinh(x/a) and arcosh(x/a) respectively
〰️ Hyperbolic Function Integrals
6 formulas Antiderivatives for sinh, cosh, tanh, and hyperbolic trigonometric forms
Hyperbolic Function Integrals
6 formulasAntiderivatives for sinh, cosh, tanh, and hyperbolic trigonometric forms
Integral of Hyperbolic Sine (sinh x)
∫ sinh(x) dx = cosh(x) + C Positive cosh(x) + C (no negative sign)
Integral of Hyperbolic Cosine (cosh x)
∫ cosh(x) dx = sinh(x) + C Direct hyperbolic antiderivative
Integral of Hyperbolic Tangent (tanh x)
∫ tanh(x) dx = ln(cosh x) + C Since cosh x > 0 for all real x, no absolute value required
Integral of Hyperbolic Secant Squared (sech² x)
∫ sech²(x) dx = tanh(x) + C Direct antiderivative yielding tanh(x)
Integral of Hyperbolic Cosecant Squared (csch² x)
∫ csch²(x) dx = -coth(x) + C Negative hyperbolic cotangent
Integral of sech(x) · tanh(x)
∫ sech(x) tanh(x) dx = -sech(x) + C Antiderivative of hyperbolic secant-tangent product
🛠️ Integration Techniques & Methods
4 formulas General analytical integration methods: Parts, Substitution, and Partial Fractions
Integration Techniques & Methods
4 formulasGeneral analytical integration methods: Parts, Substitution, and Partial Fractions
Integration by Parts Formula
∫ u dv = u·v - ∫ v du Choose u using LIATE rule (Logarithmic, Inverse trig, Algebraic, Trig, Exponential)
Integration by U-Substitution (Change of Variables)
∫ f(g(x))·g'(x) dx = ∫ f(u) du Reverses the chain rule of differentiation
Weierstrass Half-Angle Substitution (t = tan(x/2))
sin(x) = 2t1+t², cos(x) = 1-t²1+t², dx = 2dt1+t² Transforms any rational trigonometric integral into a rational polynomial algebraic integral
Logarithmic Derivative Form (∫ f'(x)/f(x) dx)
∫ (f'(x)f(x)) dx = ln|f(x)| + C Whenever numerator is exact derivative of denominator
📊 Definite Integrals & Fundamental Theorems
5 formulas Fundamental Theorem of Calculus (FTC), symmetry properties, and Leibniz rule
Definite Integrals & Fundamental Theorems
5 formulasFundamental Theorem of Calculus (FTC), symmetry properties, and Leibniz rule
Fundamental Theorem of Calculus (Part 1 - Differentiation of Integral)
ddx [ ∫xa f(t) dt ] = f(x) Connects differentiation and integration as inverse mathematical operations
Fundamental Theorem of Calculus (Part 2 - Evaluation Theorem)
∫ba f(x) dx = F(b) - F(a) Evaluates net area and accumulated change over interval [a, b]
Leibniz Rule for Differentiating Under the Integral Sign
ddx [ ∫v(x)u(x) f(t) dt ] = f(v(x))·v'(x) - f(u(x))·u'(x) Chain rule extended to variable lower and upper integration limits
Definite Integral Even / Odd Function Symmetry on [-a, a]
Even: ∫a-a f(x) dx = 2 ∫a0 f(x) dx, Odd: ∫a-a f(x) dx = 0 Instantaneous simplification for symmetric integration boundaries [-a, a]
Mean Value Theorem for Definite Integrals
favg = (1b - a)·∫ba f(x) dx = f(c) Calculates the true average value of a continuous function over [a, b]
🔁 Trigonometric Reduction Formulas
4 formulas Recursive reduction formulas for integrating higher trigonometric powers (sinⁿ x, cosⁿ x, tanⁿ x, secⁿ x)
Trigonometric Reduction Formulas
4 formulasRecursive reduction formulas for integrating higher trigonometric powers (sinⁿ x, cosⁿ x, tanⁿ x, secⁿ x)
Sine Power Reduction Formula
∫ sinⁿ(x) dx = -sinⁿ⁻¹(x)cos(x)n+ (n - 1n) ∫ sinⁿ⁻²(x) dx Reduces power of sine by 2 on each iteration
Cosine Power Reduction Formula
∫ cosⁿ(x) dx = cosⁿ⁻¹(x)sin(x)n+ (n - 1n) ∫ cosⁿ⁻²(x) dx Reduces power of cosine by 2 on each iteration
Tangent Power Reduction Formula
∫ tanⁿ(x) dx = tanⁿ⁻¹(x)n - 1 - ∫ tanⁿ⁻²(x) dx Fast algebraic reduction for tanⁿ(x)
Secant Power Reduction Formula
∫ secⁿ(x) dx = secⁿ⁻²(x)tan(x)n - 1 + (n - 2n - 1) ∫ secⁿ⁻²(x) dx Reduces higher powers of secant (e.g. ∫sec³ x dx)
Mathematics Formulas Suite
Algebra, geometry, series, matrices, combinatorics, vectors
🔢 Chapter 1: Algebraic Identities, Polynomials & Inequalities
9 formulas Binomial expansions, sum/difference of cubes, Vieta relations, Binomial theorem, and fundamental inequalities
Chapter 1: Algebraic Identities, Polynomials & Inequalities
9 formulasBinomial expansions, sum/difference of cubes, Vieta relations, Binomial theorem, and fundamental inequalities
Quadratic Equation Formula & Roots
x = -b ± √b² - 4ac2a Solutions to standard quadratic equation ax² + bx + c = 0; discriminant Δ = b² - 4ac determines real/complex nature
Binomial Square & Cube Expansion Identities
(a ± b)² = a² ± 2ab + b², (a ± b)³ = a³ ± 3a²b + 3ab² ± b³ Fundamental polynomial expansions of algebraic binomials
Trinomial Square Identity
(a + b + c)² = a² + b² + c² + 2(ab + bc + ca) Expansion of square of a sum of three terms
Difference & Sum of Cubes Factorization
a³ - b³ = (a - b)(a² + ab + b²), a³ + b³ = (a + b)(a² - ab + b²) Exact algebraic factorizations for sum and difference of cubic terms
Euler's Three-Variable Cubic Identity
a³ + b³ + c³ - 3abc = (a + b + c)(a² + b² + c² - ab - bc - ca) = ½(a + b + c)[(a - b)² + (b - c)² + (c - a)²] Special case: if a + b + c = 0, then a³ + b³ + c³ = 3abc
General Binomial Theorem
(x + y)ⁿ = ∑[k = 0 to n] (n!k!(n - k)!)·xⁿ⁻ᵏ·yᵏ Expands any positive integer power of a binomial sum using combinatorial coefficients
Vieta's Formulas for Polynomial Roots
Quadratic: r₁ + r₂ = -ba, r₁·r₂ = ca; Cubic: ∑ ri = -ba, ∑ ri rj = ca, r₁r₂r₃ = -da Direct relationships between polynomial roots and coefficients
AM-GM-HM Classical Means Inequality
AM ≥ GM ≥ HM ⟹ a₁ + a₂ + ... + ann ≥ ⁿ√a₁·a₂·...·an ≥ n1a₁+1a₂+ ... +1an Equality holds if and only if all elements a₁ = a₂ = ... = a_n
Cauchy-Schwarz Inequality
(∑[i = 1 to n] ai·bi)² ≤ (∑[i = 1 to n] ai²)·(∑[i = 1 to n] bi²) Universal inequality in real/complex inner product spaces
📐 Chapter 2: 2D Coordinate Geometry & Conic Sections
8 formulas Distance, section formulas, straight lines, circles, parabolas, ellipses, and hyperbolas
Chapter 2: 2D Coordinate Geometry & Conic Sections
8 formulasDistance, section formulas, straight lines, circles, parabolas, ellipses, and hyperbolas
2D Euclidean Distance & Section Formula
d = √(x₂ - x₁)² + (y₂ - y₁)², x = m·x₂ ± n·x₁m ± n Straight-line distance and internal/external ratio division of line segment connecting (x₁, y₁) and (x₂, y₂)
Shoelace Triangle & Polygon Area Formula
Area = ½·|x₁(y₂ - y₃) + x₂(y₃ - y₁) + x₃(y₁ - y₂)| Calculates planar area from coordinates of 3 vertices; zero area implies collinearity
Straight Line Equations & Perpendicular Distance
y - y₁ = m·(x - x₁), dperp = |A·x₀ + B·y₀ +C|√A² + B² Point-slope equation and shortest perpendicular distance from point (x₀, y₀) to line Ax + By + C = 0
Angle Between Two Intersecting Lines
tan(θ) = |(m₂ - m₁)1 + m₁·m₂| Acute intersection angle; parallel lines have m₁ = m₂; perpendicular lines have m₁·m₂ = -1
Circle Standard & General Form
(x - h)² + (y - k)² = r², x² + y² + 2gx + 2fy + c = 0 ⟹ r = √g² + f² - c Circle equation with center (h, k) and radius r
Parabola Standard Form & Eccentricity
y² = 4ax, Focus: (a, 0), Directrix: x = -a, Latus Rectum: 4a, e = 1 Locus of points equidistant from focus and directrix (eccentricity e = 1)
Ellipse Standard Form, Eccentricity & Area
x²a²+y²b² = 1, e = √1 -b²a², Foci: (±ae, 0), Area = π·a·b Standard horizontal ellipse with semi-major axis a, semi-minor axis b, and eccentricity e < 1
Hyperbola Standard Form & Asymptotes
x²a²-y²b² = 1, e = √1 +b²a², Asymptotes: y = ±(ba)·x Conic section with eccentricity e > 1 and linear asymptotes passing through origin
🧊 Chapter 3: 3D Solid Geometry & Mensuration
6 formulas 3D distance, spheres, cylinders, cones, frustums, toroids, and 3D plane equations
Chapter 3: 3D Solid Geometry & Mensuration
6 formulas3D distance, spheres, cylinders, cones, frustums, toroids, and 3D plane equations
3D Distance Formula & Sphere Equation
d = √(x₂ - x₁)² + (y₂ - y₁)² + (z₂ - z₁)², (x - x₀)² + (y - y₀)² + (z - z₀)² = R² Euclidean distance in 3D cartesian space and sphere equation with center (x₀, y₀, z₀) and radius R
Sphere & Cylinder Mensuration Formulas
Sphere: V = (43)·π·R³, A = 4·π·R²; Cylinder: V = π·r²·h, Atotal = 2·π·r·(r + h) Volumetric capacity and total surface area formulas for solid 3D spheres and cylinders
Right Circular Cone & Frustum Volume
Cone: V = (13)·π·r²·h, l = √r² + h²; Frustum: V = (13)·π·h·(R² + r² + R·r) Slant height l, lateral surface area A_lat = π·r·l, and truncated cone frustum volume
Torus (Donut) Volume & Surface Area
Vtorus = 2·π²·R·r², Atorus = 4·π²·R·r Solid of revolution generated by revolving a circle of radius r around an axis at major radius R from center (R ≥ r)
3D Plane Equation & Normal Vector
A·(x - x₀) + B·(y - y₀) + C·(z - z₀) = 0 ⟹ Ax + By + Cz + D = 0 Equation of plane passing through point (x₀, y₀, z₀) with normal vector n = <A, B, C>
Shortest Distance Between Skew Lines in 3D
d = |(a₂ - a₁)·(b₁ × b₂)||b₁ × b₂| Calculates absolute shortest distance between two non-intersecting, non-parallel 3D lines r₁ = a₁ + λb₁ and r₂ = a₂ + μb₂
📊 Chapter 4: Linear Algebra & Matrix Theory
5 formulas Determinants, matrix inverses, Cramer rule, eigenvalues, eigenvectors, and Cayley-Hamilton theorem
Chapter 4: Linear Algebra & Matrix Theory
5 formulasDeterminants, matrix inverses, Cramer rule, eigenvalues, eigenvectors, and Cayley-Hamilton theorem
Matrix Determinant (2×2 and 3×3)
det(A2x2) = ad - bc, det(A3x3) = a(ei - fh) - b(di - fg) + c(dh - eg) Scalar value scaling volume under linear transformation; det(A) = 0 indicates non-invertible singular matrix
Matrix Inverse & Adjugate Formula
A⁻¹ = (1det(A))·adj(A) = (1det(A))·(C)^T Matrix inverse where adj(A) is the transpose of the cofactor matrix C
Cramer's Rule for Linear Systems
xi = det(Ai)det(A) Explicit algebraic formula for solving system of n linear equations Ax = b where A_i has column i replaced by b
Eigenvalues & Characteristic Equation
det(A - λ·I) = 0, (A - λ·I)·v = 0 Characteristic polynomial roots yield scalar eigenvalues λ; corresponding non-zero vectors v are eigenvectors
Trace & Determinant Eigenvalue Relations
tr(A) = ∑[i = 1 to n] λi = ∑[i = 1 to n] aii, det(A) = ∏[i = 1 to n] λi Matrix trace equals sum of eigenvalues; determinant equals product of all eigenvalues
🧭 Chapter 5: Vector Calculus & Field Operators
5 formulas Dot and cross products, triple products, gradient, divergence, curl, and Laplacian
Chapter 5: Vector Calculus & Field Operators
5 formulasDot and cross products, triple products, gradient, divergence, curl, and Laplacian
Vector Dot (Scalar) & Cross (Vector) Products
u·v = |u||v|·cos(θ) = ux vx + uy vy + uz vz, |u × v| = |u||v|·sin(θ) Fundamental vector products: dot product yields scalar projection; cross product yields orthogonal vector
Triple Products (Scalar Triple & BAC-CAB Rule)
[u v w] = u·(v × w), a × (b × c) = b·(a·c) - c·(a·b) Scalar triple product computes volume of parallelepiped; BAC-CAB rule expands double cross products
Gradient of a Scalar Field (∇f)
∇f = (∂f∂x)·î + (∂f∂y)·ĵ + (∂f∂z)·k̂ Vector pointing in the direction of maximum rate of increase of scalar function f; magnitude equals maximum slope
Divergence (∇·F) & Curl (∇×F) of Vector Fields
∇·F = ∂Fx∂x+∂Fy∂y+∂Fz∂z, ∇ × F = (∂Fz∂y-∂Fy∂z)·î + (∂Fx∂z-∂Fz∂x)·ĵ + (∂Fy∂x-∂Fx∂y)·k̂ Divergence measures outward flux density (∇·F = 0 is solenoidal); Curl measures rotational vorticity (∇×F = 0 is irrotational)
Laplacian Operator (∇²f)
∇²f = ∇·(∇f) = ∂²f∂x² + ∂²f∂y² + ∂²f∂z² Second-order differential operator governing harmonic potentials, heat diffusion, and wave propagation
🔄 Chapter 6: Multivariable Integral Theorems
4 formulas Green's theorem, Stokes' theorem, Gauss divergence theorem, and Jacobians
Chapter 6: Multivariable Integral Theorems
4 formulasGreen's theorem, Stokes' theorem, Gauss divergence theorem, and Jacobians
Green's Theorem in the Plane
∮[C] (L dx + M dy) = ∬[D] (∂M∂x - ∂L∂y) dA Relates counterclockwise line integral around positively oriented simple closed curve C to double integral over enclosed region D
Stokes' Curl Theorem
∮[C] F·dr = ∬[S] (∇ × F)·dS Relates circulation line integral along boundary curve C to surface flux integral of curl ∇×F over orientable surface S
Gauss's Divergence Theorem
∯[S] F·dS = ∭[V] (∇·F) dV Outward net flux of vector field F across closed surface S equals volume integral of divergence ∇·F throughout interior volume V
Jacobian Determinant for Coordinate Substitution
J = ∂(x, y)∂(u, v) = (∂x∂u)(∂y∂v) - (∂x∂v)(∂y∂u), dx dy = |J| du dv Area/volume scaling factor during multivariable change of variables (Polar: J = r; Spherical: J = ρ² sin φ)
🌐 Chapter 7: Complex Numbers & Complex Analysis
4 formulas Euler formula, De Moivre theorem, Cauchy-Riemann analyticity, and Cauchy residue theorem
Chapter 7: Complex Numbers & Complex Analysis
4 formulasEuler formula, De Moivre theorem, Cauchy-Riemann analyticity, and Cauchy residue theorem
Complex Polar, Modulus & Euler Representation
z = x + iy = r·(cos(θ) + i·sin(θ)) = r·e^(iθ), r = √x² + y², θ = tan⁻¹(yx) Geometric representation of complex number in Argand plane
De Moivre's Theorem & n-th Roots of Unity
(cos(θ) + i·sin(θ))ⁿ = cos(nθ) + i·sin(nθ) = e^(inθ), zk = ⁿ√r·e^(i(θ + 2kπ)n) Computes integer/fractional powers and symmetric n-th roots in the complex plane
Cauchy-Riemann Analyticity Equations
∂u∂x = ∂v∂y, ∂u∂y = -(∂v∂x) Necessary and sufficient conditions for complex function f(z) = u(x, y) + i·v(x, y) to be holomorphic / complex-differentiable
Cauchy's Integral Formula & Residue Theorem
f(z₀) = (12πi)·∮[C] (f(z)z - z₀) dz, ∮[C] f(z) dz = 2πi·∑ Res(f, zk) Evaluates contour integrals via enclosed singularities and residues Res(f, z₀) = lim[z→z₀] (z - z₀)f(z)
📈 Chapter 8: Sequences, Infinite Series & Fourier Analysis
4 formulas Geometric and AGP series, Taylor and Maclaurin expansions, and Fourier series
Chapter 8: Sequences, Infinite Series & Fourier Analysis
4 formulasGeometric and AGP series, Taylor and Maclaurin expansions, and Fourier series
Geometric Progression (Finite & Infinite Sum)
Sn = a·(1 - rⁿ)1 - r, S_∞ = a1 - r (|r| < 1) Sum of geometric progression with first term a and common ratio r
Taylor & Maclaurin Series Expansion
f(x) = ∑[n = 0 to ∞] (fⁿ(a)n!)·(x - a)ⁿ = f(a) + f'(a)(x - a) + (f''(a)2!)(x - a)² + ... Representation of smooth function as infinite polynomial sum of derivatives at expansion point a (Maclaurin when a = 0)
Standard Maclaurin Series (eˣ, sin x, cos x, ln(1+x))
eˣ = 1 + x +x²2!+x³3!+ ..., sin x = x -x³3!+x⁵5!- ..., cos x = 1 -x²2!+x⁴4!- ... Infinite power series representations with infinite radius of convergence (R = ∞)
Fourier Series Expansion of Periodic Function
f(x) = a₀2+ ∑[n = 1 to ∞] [an·cos(nπxL) + bn·sin(nπxL)] Decomposes periodic waveform of period 2L into infinite sum of harmonic sinusoidal orthogonal components
⚡ Chapter 9: Differential Equations (ODE & PDE)
4 formulas First-order integrating factors, second-order constant coefficient ODEs, Laplace transforms, and PDEs
Chapter 9: Differential Equations (ODE & PDE)
4 formulasFirst-order integrating factors, second-order constant coefficient ODEs, Laplace transforms, and PDEs
1st Order Linear ODE (Integrating Factor Method)
dydx + P(x)·y = Q(x) ⟹ y·e^(∫ P dx) = ∫ Q(x)·e^(∫ P dx) dx + C General solution method using integrating factor I(x) = exp(∫P dx)
2nd Order Linear Homogeneous ODE (Characteristic Roots)
a·y'' + b·y' + c·y = 0 ⟹ a·λ² + b·λ + c = 0, λ = -b ± √b² - 4ac2a Roots determine solution form: distinct real (C₁e^λ₁x + C₂e^λ₂x), repeated ((C₁ + C₂x)e^λx), complex α±iβ (e^αx(C₁cos βx + C₂sin βx))
Laplace Transform & Derivative Property
L{f(t)} = F(s) = ∫∞0 e^(-st)·f(t) dt, L{f'(t)} = s·F(s) - f(0) Transforms linear differential equations into algebraic equations in complex frequency s-domain
Classical Partial Differential Equations (Wave, Heat, Laplace)
Wave: ∂²u∂t² = c²·(∂²u∂x²); Heat: ∂u∂t = α·(∂²u∂x²); Laplace: ∂²u∂x² + ∂²u∂y² = 0 Three fundamental linear second-order partial differential equations governing physics and engineering
🎲 Chapter 10: Probability & Statistical Distributions
5 formulas Bayes theorem, expected value, variance, Binomial, Poisson, and Gaussian Normal distributions
Chapter 10: Probability & Statistical Distributions
5 formulasBayes theorem, expected value, variance, Binomial, Poisson, and Gaussian Normal distributions
Bayes' Theorem & Law of Total Probability
P(A | B) = P(B | A)·P(A)P(B) = P(B | A)·P(A)∑ P(B | Ai)·P(Ai) Calculates posterior probability P(A|B) given prior probability P(A) and conditional likelihood P(B|A)
Expected Value & Variance Relations
E[X] = ∑ xi·P(xi), Var(X) = E[X²] - (E[X])² = σ², SD(X) = σ = √Var(X) First and second central moments measuring mean center and dispersion around the mean
Binomial Probability Distribution
P(X = k) = (n!k!(n - k)!)·pᵏ·(1 - p)ⁿ⁻ᵏ, μ = n·p, σ² = n·p·(1 - p) Probability of exactly k successes in n independent Bernoulli trials with success probability p
Poisson Probability Distribution
P(X = k) = λᵏ·e^(-λ)k!, μ = λ, σ² = λ Models rare discrete event occurrences in fixed interval of time/space with constant average rate λ
Gaussian Normal Distribution & Z-Score
f(x) = (1σ·√2π)·e^(-(x - μ)²2σ²), Z = X - μσ Continuous symmetric bell-shaped probability density function governing Central Limit Theorem
Physics Formulas Suite
Mechanics, electromagnetism, optics, thermodynamics, quantum
🏃 Chapter 1: Kinematics & 1D/2D Motion
13 formulas Equations of motion, displacement, average & instantaneous velocity, acceleration, and projectile trajectory
Chapter 1: Kinematics & 1D/2D Motion
13 formulasEquations of motion, displacement, average & instantaneous velocity, acceleration, and projectile trajectory
Average Velocity
vavg = ΔxΔt = xf - xitf - ti Ratio of total displacement to the total time interval taken
Instantaneous Velocity
v = dxdt = lim[Δt→0] (ΔxΔt) First time derivative of position coordinate vector with respect to time
Instantaneous Acceleration
a = dvdt = d²xdt² = v·(dvdx) Rate of change of velocity with respect to time or position
SUVAT 1st Equation of Motion (Velocity-Time)
v = u + a·t Relates final velocity to initial velocity under uniform acceleration a
SUVAT 2nd Equation of Motion (Displacement-Time)
s = u·t + ½·a·t² Computes total linear displacement under constant acceleration
SUVAT 3rd Equation of Motion (Velocity-Displacement)
v² = u² + 2·a·s Time-independent kinematic relation for constant acceleration
Displacement in the n-th Second
sn = u + (a2)·(2n - 1) Calculates displacement during specifically the n-th second of motion
Displacement using Average Velocity
s = ½·(u + v)·t Valid for motion under uniform constant linear acceleration
Projectile Maximum Height
Hmax = u²·sin²θ2g Peak vertical altitude reached by a projectile launched at angle θ
Projectile Total Time of Flight
T = 2u·sinθg Total airborne time from launch to landing on level ground
Projectile Horizontal Range
R = u²·sin(2θ)g Maximum horizontal distance traveled (maximum at launch angle θ = 45°)
Projectile Parabolic Trajectory Equation
y = x·tanθ -g·x²2u²·cos²θ = x·tanθ·(1 -xR) Cartesian path coordinates (x, y) demonstrating pure parabolic motion
Relative Velocity Vector
v_(AB) = vA - vB, v_(AB) = √vA² + vB² - 2vA·vB·cosθ Velocity of body A observed from the reference frame of moving body B
⚖️ Chapter 2: Laws of Motion, Friction & Circular Dynamics
12 formulas Newton's three laws, linear momentum, impulse, static/kinetic friction, centripetal force, and banking angles
Chapter 2: Laws of Motion, Friction & Circular Dynamics
12 formulasNewton's three laws, linear momentum, impulse, static/kinetic friction, centripetal force, and banking angles
Linear Momentum
p = m·v Product of mass and velocity; conserved in isolated systems with zero external force
Newton's Second Law of Motion
Fnet = dpdt = m·a (for constant mass) Net external force equals the instantaneous rate of change of linear momentum
Impulse-Momentum Theorem
J = ∫ F dt = Favg·Δt = Δp = m·vf - m·vi The impulse of a force over duration Δt equals the total change in momentum produced
Maximum Static Limiting Friction
fs(max) = μs·N Self-adjusting resistive force opposing the tendency of relative motion up to threshold
Kinetic / Sliding Friction
fk = μk·N Constant resistive force opposing active relative sliding motion (typically μ_k < μ_s)
Angle of Friction & Angle of Repose
tan(θrepose) = μs, tan(λ) = fs(max)N = μs Minimum incline tilt angle at which a body begins to slide down under gravity
Centripetal Acceleration
ac = v²r = ω²·r = v·ω = 4π²·rT² Inward radially directed acceleration for circular trajectory of radius r
Centripetal Force
Fc = m·v²r = m·ω²·r Net inward force required to maintain circular trajectory motion
Optimum Safe Speed on Banked Curved Road
vopt = √r·g·tanθ Speed at which a vehicle negotiates a turn with zero side friction wear
Maximum Safe Speed on Banked Road with Friction
vmax = √[r·g·(μs + tanθ)1 - μs·tanθ ] Upper speed limit before outward skidding occurs on banked surface with friction
Conical Pendulum Time Period
T = 2π·√L·cosθg, Tension: Tstring = m·gcosθ Period of bob describing horizontal circle of cone angle θ and string length L
Vertical Circular Motion Critical Speeds
vbottom ≥ √5gr, vtop ≥ √gr, Tbottom - Ttop = 6mg Minimum threshold speeds to complete a vertical loop without string slackening
⚡ Chapter 3: Work, Energy, Power & Collisions
11 formulas Work-energy theorem, kinetic/potential energy, spring elasticity, conservative forces, power, and elastic/inelastic collisions
Chapter 3: Work, Energy, Power & Collisions
11 formulasWork-energy theorem, kinetic/potential energy, spring elasticity, conservative forces, power, and elastic/inelastic collisions
Work Done by Constant Force
W = F·d·cosθ = F·d Scalar dot product of force vector and displacement vector
Work Done by Variable Force (Integral)
W = ∫xfxi F(x) dx Area under the Force-Displacement graph between initial and final positions
Work-Energy Theorem
Wnet = ΔK = Kf - Ki = ½m·vf² - ½m·vi² Net work done by all forces (conservative, non-conservative, external) equals change in kinetic energy
Kinetic Energy (Relation with Momentum)
K = ½·m·v² = p²2m, p = √2m·K Energy possessed by a body due to its state of motion
Gravitational Potential Energy (Near Earth)
Ug = m·g·h Potential energy stored in a mass m raised to vertical height h in uniform field g
Elastic Potential Energy of Spring (Hooke's Law)
Us = ½·k·x², Fspring = -k·x Energy stored when a spring of stiffness constant k is stretched/compressed by x
Conservative Force as Negative Potential Gradient
F = -dUdx, Fvec = -∇U = -(∂U∂x i + ∂U∂y j + ∂U∂z k) Conservative forces always point in the direction of steepest potential energy decrease
Mechanical Power (Average & Instantaneous)
P = dWdt = F·v·cosθ = F·v Time rate at which mechanical work is performed or energy transferred
Coefficient of Restitution (Collisions)
e = v₂ - v₁u₁ - u₂ = Relative velocity of separationRelative velocity of approach Measures elasticity: e=1 (kinetic energy conserved), e=0 (objects stick together)
Final Velocities in 1D Elastic Collision
v₁ = [m₁ - m₂m₁ + m₂]·u₁ + [2m₂m₁ + m₂]·u₂, v₂ = [2m₁m₁ + m₂]·u₁ + [m₂ - m₁m₁ + m₂]·u₂ Exact post-collision speeds for two masses colliding elastically in 1 dimension
Loss of Kinetic Energy in Inelastic Collision
ΔKloss = ½·[m₁·m₂m₁ + m₂ ]·(u₁ - u₂)²·(1 - e²) Kinetic energy converted into internal thermal deformation and acoustic energy
🔄 Chapter 4: Rotational Motion & Moment of Inertia
11 formulas Torque, angular momentum, rotational kinematics, parallel/perpendicular axes theorems, and rolling dynamics
Chapter 4: Rotational Motion & Moment of Inertia
11 formulasTorque, angular momentum, rotational kinematics, parallel/perpendicular axes theorems, and rolling dynamics
Center of Mass Coordinates
rcm = ∑ mi·ri∑ mi = (1M) ∫ r dm Mean position of mass distribution for discrete or continuous solid bodies
Rotational Kinematic Equations
ω = ω₀ + α·t, θ = ω₀·t + ½α·t², ω² = ω₀² + 2α·θ Rotational equivalents of SUVAT for constant angular acceleration α
Torque (Moment of Force)
τ = r × F = r·F·sinθ = I·α = dLdt Rotational equivalent of linear force causing angular acceleration α
Angular Momentum & Conservation
L = r × p = I·ω, τnet = 0 ⟹ L = const Conserved when net external torque acting on the system is zero (e.g. figure skater)
Parallel Axis Theorem (Steiner)
I = Icm + M·d² Moment of inertia about any axis parallel to centroidal axis separated by distance d
Perpendicular Axis Theorem (Planar Laminas)
Iz = Ix + Iy Applies exclusively to 2D planar bodies lying in the xy-plane
Radius of Gyration
k = √IM, I = M·k² Effective radial distance at which entire mass could be concentrated without altering I
Rotational Kinetic Energy
Krot = ½·I·ω² Kinetic energy associated exclusively with rotational spin about fixed or moving axis
Total Kinetic Energy in Pure Rolling Motion
Ktotal = Ktrans + Krot = ½M·vcm² + ½Icm·ω² = ½M·vcm²·(1 +k²R²) Combined translational and rotational kinetic energy for pure rolling without slipping (v_cm = ωR)
Acceleration of Body Rolling Down Incline
a = g·sinθ1 + IcmM·R² = g·sinθ1 +k²R² Linear acceleration down an inclined plane of slope θ (Solid Sphere > Disc > Ring)
Standard Moments of Inertia Reference
Thin Rod: 112 ML², Ring: MR², Solid Disc: ½MR²,Solid Sphere: 25 MR²,Hollow Sphere: 23 MR² Centroidal moments of inertia for standard uniform geometric bodies
🪐 Chapter 5: Universal Gravitation & Orbital Mechanics
10 formulas Newton's universal law of gravitation, gravitational potential, escape velocity, orbital velocity, Kepler's laws, and satellite orbits
Chapter 5: Universal Gravitation & Orbital Mechanics
10 formulasNewton's universal law of gravitation, gravitational potential, escape velocity, orbital velocity, Kepler's laws, and satellite orbits
Newton's Law of Universal Gravitation
F = G·(M·m)r² Inverse-square attraction between any two point masses separated by distance r
Surface Gravitational Acceleration
g = G·MR² = (43)·π·G·ρ·R Free fall acceleration at the surface of a planetary sphere of mass M and radius R
Variation of Gravity with Altitude h
gh = g·(RR + h)² ≈ g·(1 -2hR) [for h ≪ R] Decrease of gravitational acceleration with height h above planetary surface
Variation of Gravity with Depth d
gd = g·(1 -dR) Linear decrease of gravitational acceleration inside Earth (becomes zero at center d = R)
Gravitational Potential Energy (Universal)
U(r) = -G·M·mr Negative bound state energy with reference zero at infinite separation r → ∞
Gravitational Potential V(r)
V(r) = -G·Mr, Eg = -dVdr Work done in bringing unit test mass from infinity to distance r
Escape Velocity
vesc = √2G·MR = √2g·R Minimum initial speed required for an unpowered projectile to escape planetary gravity (~11.2 km/s for Earth)
Orbital Velocity of Satellite
vorb = √G·MR + h = vesc√2 (near surface) Circular speed required for stable orbit around planet (~7.92 km/s near Earth surface)
Satellite Orbital Time Period
T = 2π·(R + h)^(32)√GM = 2π·√r³GM Time required for a satellite to complete one full revolution (24 hrs for Geostationary orbit at h ~35,786 km)
Kepler's Third Law (Harmonic Law)
T²a³ = 4π²G·M = const The square of orbital period is strictly proportional to the cube of semi-major axis a
🧱 Chapter 6: Mechanical Properties of Solids & Elasticity
5 formulas Hooke's law, stress, strain, Young's modulus, bulk modulus, shear modulus, Poisson's ratio, and elastic energy density
Chapter 6: Mechanical Properties of Solids & Elasticity
5 formulasHooke's law, stress, strain, Young's modulus, bulk modulus, shear modulus, Poisson's ratio, and elastic energy density
Hooke's Law & Young's Modulus
Stress = Y·Strain ⟹ FA = Y·(ΔLL) Linear relationship between tensile/compressive stress and longitudinal strain within elastic limit
Bulk Modulus & Compressibility
B = - V·(ΔPΔV), K = 1B Resistance of substance to uniform volumetric compression under hydrostatic pressure ΔP
Shear Modulus (Modulus of Rigidity)
G = η = FAθ = F·LA·Δx Resistance to angular tangential shear distortion θ without volume alteration
Poisson's Ratio
ν = -Lateral StrainLongitudinal Strain = -ΔddΔLL Ratio of transverse contraction to longitudinal expansion (theoretical limits: -1 < ν < 0.5; practical: 0 to 0.5)
Elastic Strain Energy Density
u = ½·Stress·Strain = ½·Y·(Strain)² = (Stress)²2Y Elastic potential energy stored per unit volume in a deformed elastic material
💧 Chapter 7: Fluid Mechanics, Hydrostatics & Viscosity
10 formulas Hydrostatic pressure, Archimedes' buoyancy, continuity equation, Bernoulli's theorem, Torricelli efflux, Stokes' law, terminal velocity, and surface tension
Chapter 7: Fluid Mechanics, Hydrostatics & Viscosity
10 formulasHydrostatic pressure, Archimedes' buoyancy, continuity equation, Bernoulli's theorem, Torricelli efflux, Stokes' law, terminal velocity, and surface tension
Hydrostatic Pressure with Depth
P = P₀ + ρ·g·h Total absolute pressure at depth h in static fluid of density ρ
Pascal's Principle (Hydraulic Lift)
P₁ = P₂ ⟹ F₁A₁ = F₂A₂ Pressure applied to enclosed incompressible fluid is transmitted undiminished equally
Archimedes' Buoyancy Principle
FB = ρfluid·Vsubmerged·g = Weight of displaced fluid Upward buoyant force equal to the weight of fluid displaced by submerged object
Equation of Continuity (Conservation of Mass)
A₁·v₁ = A₂·v₂ = dVdt = Q (Flow Rate) For steady incompressible fluid flow, volumetric discharge rate Q remains constant
Bernoulli's Theorem (Conservation of Energy)
P + ½·ρ·v² + ρ·g·h = constant Sum of static pressure, dynamic kinetic pressure, and hydrostatic potential is constant along a streamline
Torricelli's Law of Efflux Speed
vefflux = √2·g·h Speed of liquid issuing from a small orifice tank opening at depth h below open surface
Stokes' Law of Viscous Drag
Fv = 6π·η·r·v Retarding viscous drag force experienced by a small sphere moving through laminar fluid
Terminal Velocity of Falling Sphere
vt = 2·r²·(ρ - σ)·g9η Steady constant velocity attained when gravity equals buoyant force + viscous drag
Excess Pressure in Droplet & Bubble
ΔPdrop = 2TR, ΔPbubble = 4TR Young-Laplace excess internal pressure: soap bubble has 2 free liquid-air interfaces
Capillary Ascent / Depression (Jurin’s Law)
h = 2T·cosθρ·g·r Height liquid rises in a narrow capillary tube of radius r with contact angle θ
🌡️ Chapter 8: Thermal Physics & Kinetic Theory of Gases
7 formulas Thermal expansion, calorimetry, ideal gas law, kinetic theory pressure, molecular speeds (RMS/avg/mp), and molar heat capacities
Chapter 8: Thermal Physics & Kinetic Theory of Gases
7 formulasThermal expansion, calorimetry, ideal gas law, kinetic theory pressure, molecular speeds (RMS/avg/mp), and molar heat capacities
Thermal Expansion (Linear, Superficial, Volumetric)
ΔL = α·L₀·ΔT, ΔA = 2α·A₀·ΔT, ΔV = 3α·V₀·ΔT = γ·V₀·ΔT Fractional dimensional expansion proportional to temperature increase ΔT (β = 2α, γ = 3α)
Sensible Heat & Latent Heat of Phase Change
Q = m·c·ΔT, Qphase = m·L Heat required to raise temperature or effect isothermal solid/liquid/gas phase transition
Ideal Gas State Equation
P·V = n·R·T = N·kB·T Constitutive equation relating pressure, volume, temperature, and quantity of ideal gas
Kinetic Theory of Gas Pressure
P = ⅓·ρ·vrms² = ⅓·(N·mV)·vrms² Microscopic statistical derivation of macroscopic gas pressure from molecular momentum collisions
RMS, Average & Most Probable Gas Speeds
vrms = √3RTM, vavg = √8RTπM, vmp = √2RTM Characteristic Maxwell-Boltzmann molecular velocity distribution speeds (v_rms > v_avg > v_mp)
Internal Energy & Degrees of Freedom
U = (f2)·n·R·T, Ek(per molecule) = (f2)·kB·T Equipartition theorem: each quadratic degree of freedom f contributes ½ k_B T per molecule
Mayer's Relation & Heat Capacity Ratio γ
Cp - Cv = R, γ = CpCv = 1 + (2f) Relation between molar heat capacities at constant pressure (C_p) and constant volume (C_v)
🔥 Chapter 9: Thermodynamics & Heat Transfer
10 formulas First law of thermodynamics, thermodynamic work processes (isothermal, adiabatic, isobaric, isochoric), Carnot engine efficiency, Stefan-Boltzmann law, and Wien displacement
Chapter 9: Thermodynamics & Heat Transfer
10 formulasFirst law of thermodynamics, thermodynamic work processes (isothermal, adiabatic, isobaric, isochoric), Carnot engine efficiency, Stefan-Boltzmann law, and Wien displacement
First Law of Thermodynamics
ΔU = Q - W ⟹ Q = ΔU + W, W = ∫ P dV Conservation of energy for thermodynamic systems (Q into system, W work done by system)
Work Done in Isothermal Process (T = const, ΔU = 0)
Wiso = n·R·T·ln(VfVi) = n·R·T·ln(PiPf) Quasistatic reversible expansion/compression at strictly constant temperature
Adiabatic Process & Work Done (Q = 0, PV^γ = const)
P·V^γ = const, Wadi = Pi·Vi - Pf·Vfγ - 1 = n·R·(Ti - Tf)γ - 1 Reversible process with zero heat exchange with surroundings (T V^(γ-1) = const)
Isobaric (P = const) & Isochoric (V = const) Work
Wisobaric = P·ΔV = n·R·ΔT, Wisochoric = 0 (since dV = 0) Under constant pressure, work is rectangular area PΔV; under constant volume, zero work is performed
Carnot Heat Engine Maximum Efficiency
η = WoutQin = 1 - (QCQH) = 1 - (TCTH) Theoretical upper thermodynamic limit on efficiency operating between temperatures T_H and T_C
Coefficient of Performance (Refrigerator / Heat Pump)
COPref = QCW = TCTH - TC, COPhp = QHW = THTH - TC Cooling or heating output energy delivered per unit of mechanical compressor work input
Thermal Conduction (Fourier's Law)
dQdt = k·A·(TH - TC)L Rate of steady-state heat conduction across a slab of thermal conductivity k and thickness L
Stefan-Boltzmann Law of Thermal Radiation
P = e·σ·A·(T⁴ - T₀⁴) Net radiative power radiated by a grey body of emissivity e into ambient environment at T₀
Wien's Displacement Law (Peak Wavelength)
λmax·T = b = 2.89777 × 10⁻³ m·K Peak emission wavelength of blackbody spectrum is inversely proportional to absolute temperature
Newton's Law of Cooling
dTdt = -k·(T - Tenv) ⟹ T(t) = Tenv + (T0 - Tenv)·e^(-kt) Rate of heat loss by convection/radiation is proportional to excess temperature over ambient
⏳ Chapter 10: Simple Harmonic Motion & Oscillations
8 formulas Kinematics of SHM, simple pendulum, spring-mass systems, series/parallel springs, physical pendulum, total energy, and damped oscillations
Chapter 10: Simple Harmonic Motion & Oscillations
8 formulasKinematics of SHM, simple pendulum, spring-mass systems, series/parallel springs, physical pendulum, total energy, and damped oscillations
Displacement, Velocity & Acceleration in SHM
x = A·sin(ωt + φ), v = dxdt = ω·√A² - x², a = d²xdt² = -ω²·x Fundamental kinematics of linear SHM with defining restoring condition a ∝ -x
Time Period of Simple Pendulum (Small Angles)
T = 2π·√Lg, f = (12π)·√gL Period of pendulum of length L in uniform gravitational field g (independent of bob mass m)
Time Period of Spring-Mass Oscillator
T = 2π·√mk, ω = √km Oscillation period of block mass m on horizontal or vertical frictionless spring of stiffness k
Spring Combinations (Series & Parallel)
1kseries = 1k₁+1k₂, kparallel = k₁ + k₂ Equivalent spring stiffness for multiple coupled springs in series or parallel
Physical (Compound) Pendulum Period
T = 2π·√Im·g·d = 2π·√kg² + d²g·d Oscillation of arbitrary rigid body pivoted at distance d from its center of mass
Torsion Pendulum Period
T = 2π·√Iκ, τ = -κ·θ Rotational oscillation of disc supported by wire with torsional rigidity constant κ
Total Mechanical Energy in SHM
E = K + U = ½m·v² + ½k·x² = ½k·A² = ½m·ω²·A² Total mechanical energy remains strictly constant, alternating between kinetic and potential forms
Damped Harmonic Oscillator
x(t) = A₀·e^(-γt)·cos(ω't + φ), ω' = √ω₀² - γ², γ = b2m Amplitude decays exponentially with damping attenuation factor γ under viscous resistance F = -bv
🔊 Chapter 11: Wave Motion, Sound & Acoustics
9 formulas Wave equation, wave speed on strings, sound velocity in fluids/gases, decibel intensity scale, standing waves in pipes/strings, beats, and Doppler effect
Chapter 11: Wave Motion, Sound & Acoustics
9 formulasWave equation, wave speed on strings, sound velocity in fluids/gases, decibel intensity scale, standing waves in pipes/strings, beats, and Doppler effect
Harmonic Traveling Wave Equation
y(x, t) = A·sin(k·x ∓ ω·t + φ), k = 2πλ, ω = 2π·f Transverse or longitudinal displacement of medium at coordinate x and time t (- for +x direction)
Wave Speed Relation
v = f·λ = ωk = λT Fundamental velocity relation connecting spatial wavelength and temporal frequency
Speed of Transverse Wave on Stretched String
v = √Ttensionμ, μ = mL (Linear mass density) Propagation velocity on a tensioned string governed by tension T and mass per unit length μ
Speed of Sound in Ideal Gas (Laplace Formula)
vsound = √γ·Pρ = √γ·R·TM Adiabatic acoustic wave speed in gas at temperature T (~343 m/s in air at 20°C)
Sound Intensity Level (Decibel Scale)
β = 10·log₁₀(II₀), I₀ = 10⁻¹² Wm² Logarithmic decibel scale relative to threshold of human hearing I₀
Standing Waves (Fixed String & Open Pipe)
fn = n·(v2L) = n·f₁ (n = 1, 2, 3, 4...) Harmonic frequencies for a string fixed at both ends or an organ pipe open at both ends (all harmonics present)
Standing Waves in Pipe Closed at One End
fn = (2n - 1)·(v4L) (n = 1, 2, 3... ⟹ 1f₁, 3f₁, 5f₁...) Resonant frequencies in a pipe closed at one end (supports only odd harmonics: 1st, 3rd, 5th...)
Beat Frequency
fbeat = |f₁ - f₂| Periodic constructive/destructive intensity modulation when two waves of close frequencies superpose
Doppler Effect for Sound Waves
f' = f·[v ± vobserverv ∓ vsource ] Apparent frequency shifted due to relative motion of observer (v_o) and source (v_s) through medium
⚡ Chapter 12: Electrostatics & Capacitance
11 formulas Coulomb's law, electric field, electric potential, electric dipole, Gauss's law, capacitance, series/parallel capacitors, and field energy density
Chapter 12: Electrostatics & Capacitance
11 formulasCoulomb's law, electric field, electric potential, electric dipole, Gauss's law, capacitance, series/parallel capacitors, and field energy density
Coulomb's Law of Electrostatic Force
F = (14πε₀)·(|q₁·q₂|r²) = ke·(|q₁·q₂|r²) Inverse-square electrostatic attraction or repulsion between two stationary point charges
Electric Field of Point Charge
E = Fq₀ = (14πε₀)·(qr²)·r̂ Force experienced per unit positive test charge q₀ placed in electric field
Electric Potential & Relation with Field
V = (14πε₀)·(qr), E = -dVdr = -∇V Work done in bringing unit positive test charge from infinity to distance r without acceleration
Electrostatic Potential Energy of Charge Pair
U = (14πε₀)·(q₁·q₂)r Energy stored in configuration of two charges separated by distance r (positive for like, negative for unlike)
Electric Dipole Moment, Torque & Potential Energy
p = q·2a, τ = p × E = p·E·sinθ, U = - p·E = - p·E·cosθ Dipole vector points from negative to positive charge; aligns with external field E
Gauss's Law of Electrostatics
ΦE = ∮ E·dA = Qenclosedε₀ Total electric flux through any closed Gaussian surface equals enclosed charge divided by ε₀
Electric Field of Line Charge & Infinite Sheet
Eline = λ2πε₀·r, Esheet = σ2ε₀, Econd = σε₀ Derived from Gauss law for uniform linear charge density λ and surface charge density σ
Capacitance of Parallel Plate Capacitor
C = κ·ε₀·Ad Capacitance proportional to plate area A and dielectric constant κ; inversely proportional to separation d
Capacitors in Series & Parallel Combinations
1Cseries = 1C₁+1C₂+ ..., Cparallel = C₁ + C₂ + ... In series: charge Q is identical across all capacitors; in parallel: voltage V is identical
Electrostatic Energy Stored in Capacitor
U = ½·C·V² = Q²2C = ½·Q·V Energy stored in electric field between capacitor plates charged to potential difference V
Electric Field Energy Density
uE = ½·ε₀·E² Electrostatic energy stored per unit volume of space occupied by electric field E
🔌 Chapter 13: Current Electricity & DC Circuits
9 formulas Drift velocity, Ohm's law, resistivity, temperature dependence, Kirchhoff's laws (KCL/KVL), Wheatstone bridge, internal resistance, and RC circuits
Chapter 13: Current Electricity & DC Circuits
9 formulasDrift velocity, Ohm's law, resistivity, temperature dependence, Kirchhoff's laws (KCL/KVL), Wheatstone bridge, internal resistance, and RC circuits
Electric Current & Drift Velocity
I = n·e·A·vd, vd = e·E·τm Relates macroscopic current I to microscopic electron drift velocity v_d and relaxation time τ
Current Density & Microscopic Ohm's Law
j = IA = σ·E = Eρ, σ = 1ρ = n·e²·τm Vector form of Ohm’s law connecting current density j to electric field E and conductivity σ
Resistance, Resistivity & Temperature Coefficient
R = ρ·(LA), R(T) = R₀·[1 + α·(T - T₀)] Resistance scales with length and temperature; inversely with cross-sectional area A
Ohm's Law & Electrical Power Dissipation
V = I·R, P = V·I = I²·R = V²R, H = I²·R·t Joule's heating law: electrical power dissipated as heat in a resistor R
Resistors in Series & Parallel
Rseries = R₁ + R₂ + ...,1Rparallel = 1R₁+1R₂+ ... Equivalent resistance rules for combining network elements
Cell Electromotive Force & Internal Resistance
V = Eemf - I·r, I = EemfR + r Terminal voltage V is less than open-circuit EMF ℰ due to internal resistance r during discharge
Kirchhoff's Current & Voltage Laws (KCL & KVL)
KCL (Junction): ∑ Iin = ∑ Iout, KVL (Loop): ∑ ΔV = ∑ Eemf - ∑ I·R = 0 KCL represents charge conservation; KVL represents electrostatic energy conservation in closed loops
Wheatstone Bridge Balance Condition
R₁R₂ = R₃R₄ ⟹ Igalvanometer = 0 Used in Meter Bridge and Post Office Box for precision measurement of unknown resistance
RC Circuit Charging & Discharging Transient
Charging: q(t) = Q₀·(1 - e^(-tRC)), Discharging: q(t) = Q₀·e^(-tRC), τ = R·C Capacitor charges to 63.2% of maximum Q₀ in one time constant τ = RC (discharges to 36.8%)
🧲 Chapter 14: Magnetism, Biot-Savart & Lorentz Force
10 formulas Magnetic Lorentz force, current wire force, cyclotron radius, Biot-Savart law, straight wire field, solenoid/toroid, parallel currents, and magnetic dipole torque
Chapter 14: Magnetism, Biot-Savart & Lorentz Force
10 formulasMagnetic Lorentz force, current wire force, cyclotron radius, Biot-Savart law, straight wire field, solenoid/toroid, parallel currents, and magnetic dipole torque
Magnetic Lorentz Force on Moving Charge
FB = q·(v × B) = q·v·B·sinθ Perpendicular deflecting force acting on a moving charge in magnetic field (zero work done)
Total Combined Lorentz Force (E + B Fields)
Ftotal = q·(E + v × B) Superposed force in simultaneous electric and magnetic fields (Velocity Selector: v = E/B)
Magnetic Force on Current-Carrying Conductor
F = I·(L × B) = I·L·B·sinθ Force on a straight wire of length L carrying current I placed in uniform field B
Cyclotron Orbit Radius & Frequency
r = m·vq·B, f = q·B2π·m, T = 2π·mq·B Helical/circular orbit parameters of charged particle in transverse magnetic field (frequency is velocity-independent)
Biot-Savart Law of Magnetostatics
dB = (μ₀4π)·[I·dl × r̂r²] = μ₀·I·dl·sinθ4π·r² Infinitesimal magnetic field generated by current element I dl at distance r
Magnetic Field of Long Straight Wire
B = μ₀·I2π·r Concentric circular magnetic field at radial distance r from an infinitely long straight wire
Magnetic Field of Circular Loop (Center & Axis)
Bcenter = μ₀·N·I2R, Baxis = μ₀·N·I·R²[2·(R² + x²)^(32)] Magnetic field produced by a circular coil of N turns of radius R at distance x along axis
Ampère's Circuital Law & Solenoid Field
∮ B·dl = μ₀·Iencl, Bsolenoid = μ₀·n·I (n = NL) Uniform internal axial magnetic field inside a tightly wound solenoid with n turns per unit length
Force Between Two Parallel Current-Carrying Wires
FL = μ₀·I₁·I₂2π·d Attractive force for parallel currents in same direction; repulsive for anti-parallel currents (SI Ampere definition)
Magnetic Dipole Moment & Torque on Current Loop
M = N·I·A, τ = M × B = N·I·A·B·sinθ, U = - M·B Operating principle of moving coil galvanometer, DC motors, and atomic magnetic moments
⚡ Chapter 15: Electromagnetic Induction & AC Circuits
10 formulas Faraday's law, Lenz's law, motional EMF, self/mutual inductance, magnetic energy density, RMS values, impedance in LCR circuits, resonance, and transformers
Chapter 15: Electromagnetic Induction & AC Circuits
10 formulasFaraday's law, Lenz's law, motional EMF, self/mutual inductance, magnetic energy density, RMS values, impedance in LCR circuits, resonance, and transformers
Faraday's Law of Electromagnetic Induction & Lenz's Law
Eind = - N·(dΦBdt), ΦB = B·A = B·A·cosθ Induced electromotive force equals the negative time rate of change of magnetic flux through loop (Lenz opposes cause)
Motional EMF in Moving Conductor
Emotional = B·L·v·sinθ EMF induced across ends of a conducting rod of length L moving at speed v across field B
Self-Inductance & Mutual Inductance
Eself = - L·(dIdt), Emutual = - M·(dI₁dt), Lsolenoid = μ₀·n²·A·l Opposition to change in current in a coil (self) or coupled adjacent coil (mutual)
Magnetic Energy in Inductor & Energy Density
UB = ½·L·I², uB = B²2μ₀ Potential energy stored in the magnetic field established inside an energized inductor
RMS & Peak Values of Alternating Current/Voltage
Vrms = V₀√2 ≈ 0.707 V₀, Irms = I₀√2 ≈ 0.707 I₀ Effective equivalent DC heating value for sinusoidal alternating voltage and current
Inductive & Capacitive Reactance
XL = ω·L = 2π·f·L, XC = 1ω·C = 12π·f·C Frequency-dependent AC opposition to current flow offered by inductors and capacitors
Series LCR Circuit Impedance & Phase Angle
Z = √[ R² + (XL - XC)² ], tanφ = XL - XCR Total combined AC electrical impedance opposition vector in series R-L-C circuits
Resonant Frequency & Quality Factor Q of LCR Circuit
f₀ = 12π·√L·C, Q = ω₀·LR = (1R)·√LC Resonance condition X_L = X_C where circuit impedance reaches absolute minimum Z = R and current is maximized
AC True Power & Power Factor
Pavg = Vrms·Irms·cosφ, Power Factor: cosφ = RZ Real power consumed in Watts (pure reactive circuits with cosφ = 0 consume zero average wattless power)
Transformer Turns Ratio & Efficiency
VsVp = NsNp = IpIs = k, η = PoutPin = Vs·IsVp·Ip Step-up (k > 1) or step-down (k < 1) mutual AC voltage transformation preserving power
⚛️ Chapter 16: Optics, Quantum & Modern Nuclear Physics
12 formulas Mirror/lens equations, Snell's law, Young's double slit, photoelectric effect, de Broglie matter waves, Bohr atom, radioactive decay, and mass-energy relativity
Chapter 16: Optics, Quantum & Modern Nuclear Physics
12 formulasMirror/lens equations, Snell's law, Young's double slit, photoelectric effect, de Broglie matter waves, Bohr atom, radioactive decay, and mass-energy relativity
Spherical Mirror Formula & Magnification
1f = 1v+1u, m = -vu = hiho Relates focal length f, image distance v, and object distance u with standard Cartesian sign convention
Snell's Law of Refraction & Total Internal Reflection
n₁·sinθ₁ = n₂·sinθ₂, sin(θc) = n₂n₁ (for n₁ > n₂) Bending of light ray across optical boundaries and critical angle θ_c for complete internal reflection
Lens Maker's Formula & Thin Lens Equation
1f = (n - 1)·(1R₁-1R₂),1f = 1v-1u, P = 1f(m) Computes optical power P in Diopters (D = m⁻¹) from refractive index n and radii of curvature R₁, R₂
Young's Double Slit Interference Fringe Width
β = λ·Dd, yn(bright) = n·(λ·Dd), yn(dark) = (2n - 1)·(λ·D2d) Spatial fringe spacing β between consecutive interference fringes on a screen at distance D
Einstein's Photoelectric Equation
Ephoton = h·f = Φ₀ + Kmax = h·f₀ + e·Vs Photon energy hf overcomes metal work function Φ₀ and imparts maximum kinetic energy K_max
De Broglie Wavelength of Matter Waves
λ = hp = hm·v = h√2m·K = h√2m·q·V Wave-particle duality: every moving particle has an associated quantum de Broglie wavelength
Bohr's Hydrogen Atomic Model (Energy & Radius)
rn = n²·h²·ε₀π·m·e² = 0.529·n² Å, En = -13.6n² eV Quantized electron orbital radii r_n and bound stationary energy states E_n for hydrogen-like atoms
Rydberg Formula for Hydrogen Spectral Series
1λ = RH·[1n₁²-1n₂²] (Lyman n₁ = 1, Balmer n₁ = 2, Paschen n₁ = 3) Calculates emission/absorption spectral line wavelengths in atomic transitions (n₂ > n₁)
Mass Defect & Nuclear Binding Energy
Δm = [Z·mp + (A - Z)·mn] - Mnucleus, Eb = Δm·c² = Δm(amu) × 931.5 MeV Energy required to dismantle an atomic nucleus into individual constituent protons and neutrons
Radioactive Decay Law & Half-Life
N(t) = N₀·e^(-λt), Thalf = ln(2)λ ≈ 0.693λ, A = λ·N Statistical decay rate of unstable radionuclides (Activity measured in Becquerels Bq = decays/s)
Einstein's Mass-Energy Equivalence & Relativistic Energy
E = m·c² = γ·m₀·c², E² = (p·c)² + (m₀·c²)² Invariant four-momentum energy relation connecting total relativistic energy E, momentum p, and rest mass m₀
Relativistic Time Dilation & Length Contraction
Δt = γ·Δt₀ = Δt₀√1 -v²c², L = L₀γ = L₀·√1 -v²c² Moving clocks run slower (time dilation); moving rods are shortened in the direction of motion (length contraction)
Chemistry Formulas Suite
Gas laws, stoichiometry, thermochemistry, kinetics, equilibrium
🧪 Chapter 1: Mole Concept, Stoichiometry & Concentration Terms
10 formulas Quantitative mass-mole conversions, Avogadro relation, molarity, molality, normality, ppm, and reaction yields
Chapter 1: Mole Concept, Stoichiometry & Concentration Terms
10 formulasQuantitative mass-mole conversions, Avogadro relation, molarity, molality, normality, ppm, and reaction yields
Mole Concept, Sample Mass & Particle Count
n = mM = NNA Fundamental relation converting between sample mass, moles, and elementary particles
Molar Gas Volume at STP
V = n·Vm = n·22.414 L Volume occupied by one mole of any ideal gas at Standard Temperature and Pressure
Molarity (Molar Concentration)
M = nsoluteVsolution = wB × 1000MB × VmL Number of moles of solute dissolved per liter volume of solution
Molality (Temperature-Independent Concentration)
m = nsoluteWsolvent = wB × 1000MB × WA Moles of solute per kilogram of pure solvent; does not vary with thermal temperature changes
Normality & Equivalent Weight
N = wB × 1000EB × VmL = M·nfactor Gram equivalent concentration per liter; n-factor represents acidity, basicity, or valence change
Mole Fraction & Summation Law
XA = nAnA + nB, XA + XB = 1 Dimensionless ratio of component moles to total solution moles
Mass Percentage (% w/w) & Parts Per Million (ppm)
%(ww) = (wsolutewtotal) × 100, ppm = (wsolutewtotal) × 10⁶ Trace concentration metrics used extensively in water testing and atmospheric analysis
Volumetric Solution Dilution Formula
M₁·V₁ = M₂·V₂, N₁·V₁ = N₂·V₂ Solute mole conservation during solvent dilution from initial to final volume
Percentage Yield of Chemical Reaction
% Yield = (Actual YieldTheoretical Yield) × 100 Ratio of experimentally obtained product to the stoichiometric maximum from limiting reactant
Empirical to Molecular Formula Multiplier
n = MmolecularMempirical, Molecular Formula = (Empirical Formula)n Integer multiplier scaling simplest whole-number atomic ratio to actual molecular formula
⚛️ Chapter 2: Atomic Structure, Quantum Mechanics & Radioactivity
8 formulas Bohr model orbits, Rydberg spectral transitions, de Broglie wave-particle duality, Heisenberg principle, and decay kinetics
Chapter 2: Atomic Structure, Quantum Mechanics & Radioactivity
8 formulasBohr model orbits, Rydberg spectral transitions, de Broglie wave-particle duality, Heisenberg principle, and decay kinetics
Planck-Einstein Photon Energy Relation
E = h·ν = h·cλ = h·c·νbar Quantized energy carried by an electromagnetic photon of frequency ν and wavelength λ
Bohr Hydrogen-Like Atomic Orbit Radius
rn = n²·h²·ε₀π·m·Z·e² = 0.529·(n²Z) Å Quantized orbital radius of hydrogenic atoms with nuclear atomic number Z
Bohr Electronic Energy Levels
En = -13.6·(Z²n²) eV = -2.18 × 10⁻¹⁸·(Z²n²) J Quantized total binding energy of bound electron in n-th principal shell
Rydberg Emission Spectrum Equation
1λ = RH·Z²·(1n₁²-1n₂²) Predicts spectral transition wavelengths (Lyman n₁=1, Balmer n₁=2, Paschen n₁=3, Brackett n₁=4, Pfund n₁=5)
de Broglie Matter Wavelength
λ = hp = hm·v = h√2·m·Ek = h√2·m·q·V Wave-particle duality showing that moving particles exhibit wavelength inversely proportional to momentum
Heisenberg's Uncertainty Principle
Δx·Δp ≥ h4π, ΔE·Δt ≥ h4π Fundamental quantum limit on simultaneous precision of position and conjugate momentum
Einstein's Photoelectric Kinetic Energy Equation
h·ν = Φ + Kmax = h·ν₀ + ½·m·vmax² Conservation of energy during photon absorption and photoelectron emission
Nuclear Radioactive Decay Law & Half-Life
N(t) = N₀·e^(-λ·t), t½ = ln(2)λ = 0.693λ First-order spontaneous nuclear disintegration rate and radioactive half-life
💨 Chapter 3: Gaseous State & Kinetic Molecular Theory
8 formulas Ideal gas relations, Dalton partial pressures, Graham effusion, molecular speeds, and Van der Waals real gases
Chapter 3: Gaseous State & Kinetic Molecular Theory
8 formulasIdeal gas relations, Dalton partial pressures, Graham effusion, molecular speeds, and Van der Waals real gases
Ideal Gas Law & Gas Density Relation
P·V = n·R·T, P·M = ρ·R·T Equation of state of ideal gas connecting pressure, volume, temperature, and density
Combined Gas Law (Boyle, Charles, Gay-Lussac)
P₁·V₁T₁ = P₂·V₂T₂ Unifies Boyle (PV=k), Charles (V/T=k), and Gay-Lussac (P/T=k) gas laws
Dalton's Law of Partial Pressures
Ptotal = PA + PB + PC, PA = XA·Ptotal Total pressure in a non-reacting gas mixture equals the sum of individual partial pressures
Graham's Law of Diffusion & Effusion
r₁r₂ = √M₂M₁ = √ρ₂ρ₁ = V₁t₁V₂t₂ Rate of gas effusion/diffusion through a porous pinhole is inversely proportional to square root of molar mass
RMS, Average & Most Probable Molecular Speeds
urms = √3RTM, uavg = √8RTπM, ump = √2RTM Maxwell-Boltzmann distribution speed ratios: u_mp : u_avg : u_rms = 1 : 1.128 : 1.224 = √2 : √(8/π) : √3
Kinetic Gas Energy & Mean Kinetic Energy
Ek,total = (32)·n·R·T, Ek,molecule = (32)·kB·T Total and per-molecule translational kinetic energy depending purely on absolute temperature
Van der Waals Equation for Real Gases
(P +a·n²V²)·(V - n·b) = n·R·T Corrects ideal gas law for intermolecular attractive forces (a) and excluded finite molecular volume (b)
Compressibility Factor & Critical Constants
Z = P·VmR·T, Tc = 8a27Rb, Pc = a27b², Vc = 3b Measures deviation from ideal behavior (Z=1). Above critical temperature T_c gas cannot be liquefied
🔥 Chapter 4: Chemical Thermodynamics & Thermochemistry
9 formulas First Law, Hess law, bond energies, entropy changes, Gibbs free energy, and equilibrium coupling
Chapter 4: Chemical Thermodynamics & Thermochemistry
9 formulasFirst Law, Hess law, bond energies, entropy changes, Gibbs free energy, and equilibrium coupling
First Law of Thermodynamics & Expansion Work
ΔU = q + w, w = -Pext·ΔV = -∫ Pext dV IUPAC convention: work done on the system is positive (+), work done by system is negative (-)
Reversible Isothermal Work of Ideal Gas
wrev = -n·R·T·ln(V₂V₁) = -2.303·n·R·T·log(P₁P₂) Maximum possible thermodynamic work obtained during slow quasi-static isothermal expansion
Enthalpy Definition & Gaseous Mole Relation
H = U + P·V ⟹ ΔH = ΔU + Δng·R·T Connects reaction heat at constant pressure (ΔH = q_p) and constant volume (ΔU = q_v)
Molar Heat Capacities & Mayer Relation
Cp - Cv = R, γ = CpCv, ΔH = n·Cp·ΔT, ΔU = n·Cv·ΔT Specific heat capacity relations for monoatomic (γ=1.66), diatomic (γ=1.40), and polyatomic gases
Standard Enthalpy of Reaction from Formation Enthalpies
ΔHrxn° = ∑ νp·ΔHf°(products) - ∑ νr·ΔHf°(reactants) Calculates standard reaction enthalpy (ΔH_f° of pure elements in standard states is zero)
Reaction Enthalpy from Bond Dissociation Energies
ΔHrxn = ∑ Bond Energy(broken in reactants) - ∑ Bond Energy(formed in products) Approximates gaseous reaction enthalpies from average covalent bond dissociation energies
Kirchhoff's Temperature-Enthalpy Law
ΔHT2 = ΔHT1 + ΔCp·(T₂ - T₁) Evaluates heat of reaction at varying temperatures when heat capacities are known
Gibbs Free Energy & Spontaneity Criterion
ΔG = ΔH - T·ΔS Determines thermodynamic reaction direction at constant temperature and pressure
Standard Free Energy & Equilibrium Constant Coupling
ΔG° = -R·T·ln(Keq) = -2.303·R·T·log(Keq) Fundamental link connecting chemical thermodynamic potentials to macroscopic equilibrium constants
⚖️ Chapter 5: Chemical Equilibrium & Le Chatelier Principle
5 formulas Mass action law, Kc and Kp relations, reaction quotient Q, degree of dissociation, and Van t Hoff equation
Chapter 5: Chemical Equilibrium & Le Chatelier Principle
5 formulasMass action law, Kc and Kp relations, reaction quotient Q, degree of dissociation, and Van t Hoff equation
Law of Mass Action Equilibrium Constants (Kc & Kp)
Kc = [C]^c·[D]^d[A]^a·[B]^b, Kp = PC^c·PD^dPA^a·PB^b Ratio of product concentrations to reactant concentrations raised to stoichiometric powers at equilibrium
Relation Between Kp and Kc
Kp = Kc·(R·T)^(Δng) Relates pressure and concentration equilibrium constants; if Δn_g = 0, then K_p = K_c
Reaction Quotient (Q) & Direction Criterion
Qc = [C]^c·[D]^d[A]^a·[B]^b Calculates non-equilibrium instantaneous ratio to predict spontaneous direction towards equilibrium
Van 't Hoff Temperature-Equilibrium Isochore
ln(K₂K₁) = (ΔH°R)·(1T₁-1T₂) Predicts equilibrium constant shifts with temperature (K increases with T for endothermic ΔH > 0)
Degree of Dissociation (α) from Vapor Density
α = D - d(n - 1)·d = Mtheoretical - Mobserved(n - 1)·Mobserved Fraction of initial molecules dissociated at equilibrium where n is moles of products per mole of reactant
🧪 Chapter 6: Ionic Equilibrium, Acids, Bases & Buffers
6 formulas Ostwald dilution, pH scales, Henderson-Hasselbalch buffer equations, salt hydrolysis, and Ksp solubility product
Chapter 6: Ionic Equilibrium, Acids, Bases & Buffers
6 formulasOstwald dilution, pH scales, Henderson-Hasselbalch buffer equations, salt hydrolysis, and Ksp solubility product
Ostwald's Dilution Law for Weak Electrolytes
Ka = C·α²1 - α ≈ C·α² ⟹ α = √KaC Valid for weak acids/bases when dissociation fraction α << 1
Autoionization of Water & pH-pOH Scale
Kw = [H⁺]·[OH⁻] = 1.0 × 10⁻¹⁴, pH + pOH = pKw = 14 Fundamental logarithmic scales: pH = -log₁₀[H⁺] and pOH = -log₁₀[OH⁻]
Henderson-Hasselbalch Equation (Acidic Buffer)
pH = pKa + log₁₀([Conjugate Base][Weak Acid]) = pKa + log₁₀([Salt][Acid]) Calculates pH of an acidic buffer mixture (e.g. CH₃COOH + CH₃COONa)
Henderson-Hasselbalch Equation (Basic Buffer)
pOH = pKb + log₁₀([Conjugate Acid][Weak Base]), pH = 14 - pOH Calculates pOH and pH of a basic buffer solution (e.g. NH₄OH + NH₄Cl)
Salt Hydrolysis pH Formulas
WA-SB: pH = 7 + ½pKa + ½log(C), SA-WB: pH = 7 - ½pKb - ½log(C), WA-WB: pH = 7 + ½pKa - ½pKb Calculates pH resulting from cationic/anionic hydrolysis of weak acid and weak base salts
Solubility Product Constant (Ksp) & Molar Solubility (S)
Ax By ⇌ x A^(y+) + y B^(x-) ⟹ Ksp = x^x·y^y·S^(x+y) Equilibrium constant for sparingly soluble salts (1:1 salt: K_sp = S²; 1:2 salt: K_sp = 4S³; 1:3 salt: K_sp = 27S⁴)
⏱️ Chapter 7: Chemical Kinetics & Reaction Dynamics
6 formulas Differential & integrated rate laws, half-life equations, Arrhenius activation energy, and collision theory
Chapter 7: Chemical Kinetics & Reaction Dynamics
6 formulasDifferential & integrated rate laws, half-life equations, Arrhenius activation energy, and collision theory
General Reaction Rate & Rate Law Expression
Rate = -(1a)·(d[A]dt) = (1c)·(d[C]dt) = k·[A]^m·[B]^n Overall reaction order = m + n; rate constant k has units of (mol/L)^(1-n) · s⁻¹
Zero-Order Integrated Rate Law & Half-Life
[A] = [A]₀ - k·t, t½ = [A]₀2k Rate is independent of reactant concentration; half-life is directly proportional to initial concentration
First-Order Integrated Rate Law & Half-Life
k = (2.303t)·log([A]₀[A]), [A] = [A]₀·e^(-k·t), t½ = ln(2)k = 0.693k First-order half-life is strictly independent of initial reactant concentration
Second-Order Integrated Rate Law & Half-Life
1[A] = 1[A]₀ + k·t, t½ = 1k·[A]₀ Half-life is inversely proportional to initial reactant concentration
Arrhenius Rate-Temperature Equation
k = A·e^(-EaR·T) ⟹ ln(k) = ln(A) -EaR·T Quantifies exponential rate acceleration with temperature and activation energy barrier
Two-Temperature Arrhenius Ratio Formula
log(k₂k₁) = (Ea2.303·R)·(T₂ - T₁T₁·T₂) Calculates activation energy E_a from rate constants measured at two distinct temperatures
⚡ Chapter 8: Electrochemistry & Galvanic Cells
6 formulas Standard EMF potentials, Nernst equation, Gibbs electrical work, Kohlrausch conductivity, and Faraday electrolysis laws
Chapter 8: Electrochemistry & Galvanic Cells
6 formulasStandard EMF potentials, Nernst equation, Gibbs electrical work, Kohlrausch conductivity, and Faraday electrolysis laws
Standard Cell Potential (EMF)
Ecell° = Ecathode° - Eanode° = Ereduction(RHE)° - Ereduction(LHE)° Electromotive force under standard conditions (1 M concentrations, 1 atm gas pressure, 298 K)
Nernst Equation at 298 K (25°C)
Ecell = Ecell° - (0.0591n)·log₁₀(Q) Calculates non-standard electrochemical cell potential for non-unity reactant/product activities
Gibbs Free Energy & Standard Cell Potential
ΔG° = -n·F·Ecell°, Ecell° = (0.0591n)·log₁₀(Kc) Links standard electrochemical cell potential to maximum non-expansion electrical work and equilibrium
Specific & Molar Electrolytic Conductivity
κ = G·(lA) = (1R)·G*, Λm = κ × 1000M Molar conductivity per mole of electrolyte (units: S·cm²·mol⁻¹)
Kohlrausch's Law of Independent Ion Migration
Λm° = ν₊·λ₊° + ν₋·λ₋°, α = ΛmΛm° At infinite dilution each ion contributes independently to molar conductance; determines weak electrolyte dissociation α
Faraday's Laws of Electrolysis
m = Z·I·t = M·I·tn·F,m₁E₁ = m₂E₂ Mass deposited or liberated at an electrode is proportional to charge Q (Faraday constant F = 96485 C/mol)
💧 Chapter 9: Solutions & Colligative Properties
6 formulas Raoult law of vapor pressure, boiling point elevation, freezing depression, osmotic pressure, and Van t Hoff factor
Chapter 9: Solutions & Colligative Properties
6 formulasRaoult law of vapor pressure, boiling point elevation, freezing depression, osmotic pressure, and Van t Hoff factor
Raoult's Law & Relative Lowering of Vapor Pressure
PA = XA·PA°,PA° - PAPA° = XB = nBnA + nB Relative vapor pressure lowering equals mole fraction of non-volatile solute
Boiling Point Elevation (Ebullioscopy)
ΔTb = i·Kb·m = i·(Kb × wB × 1000MB × wA) Ebullioscopic constant K_b depends solely on solvent nature: K_b = (R·T_b²·M_solvent) / (1000·ΔH_vap)
Freezing Point Depression (Cryoscopy)
ΔTf = i·Kf·m = i·(Kf × wB × 1000MB × wA) Cryoscopic constant K_f: K_f = (R·T_f²·M_solvent) / (1000·ΔH_fus) (1.86 K·kg/mol for water)
Van 't Hoff Osmotic Pressure Law
Π = i·C·R·T = i·(nBV)·R·T = i·(wB·R·T)MB·V Hydrostatic pressure required to completely prevent solvent osmosis across semi-permeable membrane
Van 't Hoff Factor (i) for Dissociation & Association
i = 1 + (n - 1)·αdiss, i = 1 + (1n- 1)·αassoc Accounts for abnormal molecular masses due to electrolyte ionization or dimerization in solution
Henry's Law of Gas Solubility in Liquid
pgas = KH·Xgas, mgas = kH·pgas Gas dissolved in liquid is directly proportional to partial pressure above the liquid (K_H increases with T)
🧊 Chapter 10: Solid State & Crystallography
4 formulas Unit cell density, cubic crystal geometries (SC, BCC, FCC), radius ratio rules, and Bragg X-ray diffraction
Chapter 10: Solid State & Crystallography
4 formulasUnit cell density, cubic crystal geometries (SC, BCC, FCC), radius ratio rules, and Bragg X-ray diffraction
Unit Cell Crystal Density Formula
ρ = z·Ma³·NA Theoretical crystal mass density from lattice edge length a and effective atom count z
Cubic Lattice Geometries & Packing Efficiencies
SC: r = a2 (52.4%), BCC: r = (√34)·a (68.0%), FCC: r = a2√2 (74.0%) Geometric relations between atomic radius r, edge length a, and space-filling packing efficiency
Limiting Radius Ratio Rules & Coordination Geometry
Linear: <0.155 (CN 2), Triangular: 0.155-0.225 (CN 3), Tetrahedral: 0.225-0.414 (CN 4), Octahedral: 0.414-0.732 (CN 6), Cubic: 0.732-1.000 (CN 8) Predicts ionic crystal coordination number (CN) and interstitial geometry from cation/anion radius ratio
Bragg's Law of X-Ray Diffraction
n·λ = 2·d·sin(θ) Constructive interference condition for monochromatic X-rays scattered by crystal lattice planes spaced d apart
🧲 Chapter 11: Surface Chemistry & Colloidal State
3 formulas Freundlich & Langmuir adsorption isotherms, Hardy-Schulze rule, and zeta potential
Chapter 11: Surface Chemistry & Colloidal State
3 formulasFreundlich & Langmuir adsorption isotherms, Hardy-Schulze rule, and zeta potential
Freundlich Adsorption Isotherm
xm = k·P^(1n) ⟹ log(xm) = log(k) + (1n)·log(P) Empirical model for gas adsorption on solid adsorbent surface over moderate pressure ranges
Langmuir Monolayer Adsorption Isotherm
xm = a·P1 + b·P ⟹ Pxm = 1a+ (ba)·P Theoretical model assuming homogeneous monolayer surface coverage and localized identical sites
Hardy-Schulze Rule for Colloidal Coagulation
Coagulating Power ∝ (Valency of Oppositely Charged Ion)⁴ Coagulating power of an electrolyte ion increases dramatically with its charge valency z
🔗 Chapter 12: Chemical Bonding & Molecular Structure
5 formulas Dipole moments, Pauling ionic character, molecular orbital bond order, formal charges, and spin-only magnetic moments
Chapter 12: Chemical Bonding & Molecular Structure
5 formulasDipole moments, Pauling ionic character, molecular orbital bond order, formal charges, and spin-only magnetic moments
Electric Dipole Moment (Debye)
μ = q·d, 1 Debye (D) = 3.33564 × 10⁻³⁰ C·m = 10⁻¹⁸ esu·cm Quantifies molecular electrical polarity from charge separation q over bond distance d
Pauling Percentage Ionic Character
% Ionic = 16·|χA - χB| + 3.5·(χA - χB)² Estimates percentage ionic character of a covalent bond from electronegativity difference Δχ
Molecular Orbital (MO) Bond Order
Bond Order = ½·(Nb - Na) Net bonding stability: Bond Order > 0 indicates stable molecule; higher bond order means shorter bond length and higher bond energy
Formal Charge on Lewis Structure Atom
FC = V - Nlone - ½·Nbonding Bookkeeping of valence electrons to determine the most stable resonance Lewis structure
Spin-Only Magnetic Moment of Transition Metal Ions
μs = √n·(n + 2) BM Calculates paramagnetic magnetic moment from number of unpaired d-electrons n (n=1: 1.73 BM, n=2: 2.83 BM, n=3: 3.87 BM, n=4: 4.90 BM, n=5: 5.92 BM)
⚗️ Chapter 13: Redox Reactions & Volumetric Titrations
3 formulas Oxidation numbers, equivalent weights, redox neutralization, and disproportionation stoichiometry
Chapter 13: Redox Reactions & Volumetric Titrations
3 formulasOxidation numbers, equivalent weights, redox neutralization, and disproportionation stoichiometry
Equivalent Weight of Oxidizing & Reducing Agents
E = Molar MassNumber of electrons gained or lost per molecule Example: KMnO₄ in acidic medium (n=5) E = M/5; in neutral medium (n=3) E = M/3; in basic medium (n=1) E = M/1
Law of Chemical Equivalents & Titration Law
N₁·V₁ = N₂·V₂ ⟹ n₁·M₁·V₁ = n₂·M₂·V₂ At the stoichiometric equivalence point, equivalents of titrant equal equivalents of analyte
Equivalent Weight in Disproportionation Reactions
Etotal = Eoxidation + Ereduction = Mn₁+Mn₂ For redox reactions where the same chemical element simultaneously undergoes oxidation and reduction
🌿 Chapter 14: Organic Chemistry Principles & Stereochemistry
4 formulas Index of Hydrogen Deficiency (IHD), specific optical rotation, enantiomeric excess, and Hammett equation
Chapter 14: Organic Chemistry Principles & Stereochemistry
4 formulasIndex of Hydrogen Deficiency (IHD), specific optical rotation, enantiomeric excess, and Hammett equation
Index of Hydrogen Deficiency (Degree of Unsaturation)
IHD = C + 1 - (H2) - (X2) + (N2) Determines total number of rings and π-bonds (double bond = 1, triple bond = 2, benzene ring = 4)
Biot's Specific Optical Rotation Law
[α]D^T = αobsl·c Standard chiral optical activity measured using Sodium D-line (589 nm) polarimetry
Enantiomeric Excess (% ee) & Optical Purity
% ee = (|R -S|R + S) × 100 = (αobsαpure) × 100 Quantifies chiral excess of one enantiomer over racemic mixture (50:50 mixture has 0% ee)
Hammett Linear Free Energy Relationship
log(KK₀) = σ·ρ, log(kk₀) = σ·ρ Relates meta/para substituent electronic effects (σ) and reaction sensitivity (ρ) to substituted benzoic acid rates
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